A new 3D Cd-triazolate framework obtained from in situ decarboxylication of 5-amino-3-carboxyl-1,2,4-triazole
作者： Bing Liu , Hui-Jun Feng , Zong-Hui Zhang , Ling Xu , Huan Jiao
DOI: 10.1016/J.MOLSTRUC.2015.06.021
关键词:
摘要: Abstract A new 3D Cd-triazolate MOF compound [Cd(Hatrz) (SO 4 )] ( 1 ) (Hatrz = 3-amino-1H-1,2,4-triazole) was obtained from in situ decarboxylication of 5-amino-3-carboxyl-1,2,4-triazole (H 2 atrc) under the hydrothermal reaction CdSO with H atrc. Compound features itself a Hatrz-supporting architecture based on connection inorganic [CdSO ] layers Hatrz spacers. Cd(II) atom, SO − and dummied as 6-, 4- 2-connected nodes respectively, can be simplified to (2,4,6)-connected {4 .6 .8 8 .12}{4 }{8} topological network. The thermal stability is up ca. 402 °C, fluorescence shows an emission at 366 nm, originating → Cd transfer. PXRD confirms phase purity bulk sample. FT-IR spectrum accord structure analysis.
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sci-hub.se 参考文章(43)
A. F. Wells, Three-dimensional nets and polyhedra ,(1977)
A Cyclic Trinuclear 1,2,4-Triazole-containing Copper(II) Complex Involving a Pyramidal Cu3(OH) Core: Synthesis, Structure and Fluorescence Bulletin of The Korean Chemical Society. ,vol. 30, pp. 2467- 2470 ,(2009) , 10.5012/BKCS.2009.30.10.2467
Jung Soo Seo, Dongmok Whang, Hyoyoung Lee, Sung Im Jun, Jinho Oh, Young Jin Jeon, Kimoon Kim, A homochiral metal-organic porous material for enantioselective separation and catalysis Nature. ,vol. 404, pp. 982- 986 ,(2000) , 10.1038/35010088
A. Corma, H. García, F. X. Llabrés i Xamena, Engineering Metal Organic Frameworks for Heterogeneous Catalysis Chemical Reviews. ,vol. 110, pp. 4606- 4655 ,(2010) , 10.1021/CR9003924
Banglin Chen, Shengchang Xiang, Guodong Qian, Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules Accounts of Chemical Research. ,vol. 43, pp. 1115- 1124 ,(2010) , 10.1021/AR100023Y
Peng Yang, Ming-Xing Li, Min Shao, Meng-Si Wang, Shi-Xun Cao, Jin-Cang Zhang, Heng-Hua Zhang, Porous and Nanorod-Like Coordination Polymers Assembled from a New V-Shaped Bis(1,2,4-triazolyl)tripyridine Ligand Crystal Growth & Design. ,vol. 13, pp. 4305- 4314 ,(2013) , 10.1021/CG400644K
David B. Mitzi, Templating and structural engineering in organic–inorganic perovskites Journal of the Chemical Society, Dalton Transactions. pp. 1- 12 ,(2001) , 10.1039/B007070J
Irena Matulková, Ivan Němec, Karel Teubner, Petr Němec, Zdeněk Mička, Novel compounds of 4-amino-1,2,4-triazole with dicarboxylic acids crystal structures, vibrational spectra and non-linear optical properties Journal of Molecular Structure. ,vol. 873, pp. 46- 60 ,(2008) , 10.1016/J.MOLSTRUC.2007.03.007
Sammer M. Tekarli, Thomas R. Cundari, Mohammad A. Omary, Rational Design of Macrometallocyclic Trinuclear Complexes with Superior π-Acidity and π-Basicity Journal of the American Chemical Society. ,vol. 130, pp. 1669- 1675 ,(2008) , 10.1021/JA076527U
JianJun Zhang, Lukasz Wojtas, Randy W. Larsen, Mohamed Eddaoudi, Michael J. Zaworotko, Temperature and concentration control over interpenetration in a metal-organic material. Journal of the American Chemical Society. ,vol. 131, pp. 17040- 17041 ,(2009) , 10.1021/JA906911Q