Properties of amidated pectins. II. Polyelectrolyte behavior and calcium binding of amidated pectins and amidated pectic acids

作者: E. Racape , J. F. Thibault , J. C. E. Reitsma , W. Pilnik

DOI: 10.1002/BIP.360280809

关键词:

摘要: The intrinsic pK values, as well the free fractions of sodium and calcium counterions, were determined on salt-free solutions amidated pectinates pectates. apparent values non dependent degree amidation but only to effective charge density pectic polymers an unique value 2.9 ± 0.1 was found for value. results obtained by conductimetry with (sodium calcium) specific electrodes showed a blockwise distribution amide acid groups in pectates rather statistical pectinates.

参考文章(15)
SHARON A. BLACK, C. J. B. SMIT, THE EFFECT OF DEMETHYLATION PROCEDURES ON THE QUALITY OF LOW-ESTER PECTINS USED IN DESSERT GELS Journal of Food Science. ,vol. 37, pp. 730- 732 ,(1972) , 10.1111/J.1365-2621.1972.TB02737.X
Rudolf Kohn, Oskar Markovič, Eva Machová, Deesterification mode of pectin by pectin esterases of Aspergillus foetidus, tomatoes and alfalfa Collection of Czechoslovak Chemical Communications. ,vol. 48, pp. 790- 797 ,(1983) , 10.1135/CCCC19830790
F. Michel, J.-F. Thibault, J.-L. Doublier, Viscometric and potentiometric study of high-methoxyl pectins in the presence of sucrose Carbohydrate Polymers. ,vol. 4, pp. 283- 297 ,(1984) , 10.1016/0144-8617(84)90004-3
R. Kohn, O. Luknár, Calcium and strontium ion activity in solutions of the corresponding pectinates and its dependence on their degree of esterification Collection of Czechoslovak Chemical Communications. ,vol. 40, pp. 959- 970 ,(1975) , 10.1135/CCCC19750959
J.A. de Vries, F.M. Rombouts, A.G.J. Voragen, W. Pilnik, Distribution of methoxyl groups in apple pectic substances Carbohydrate Polymers. ,vol. 3, pp. 245- 258 ,(1983) , 10.1016/0144-8617(83)90023-1
Gerald S. Manning, Limiting Laws and Counterion Condensation in Polyelectrolyte Solutions I. Colligative Properties The Journal of Chemical Physics. ,vol. 51, pp. 924- 933 ,(1969) , 10.1063/1.1672157