Kinetic studies of ozone assisted low temperature oxidation of dimethyl ether in a flow reactor using molecular-beam mass spectrometry
作者： Hao Zhao , Xueliang Yang , Yiguang Ju
DOI: 10.1016/J.COMBUSTFLAME.2016.08.008
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摘要: The ozone assisted low temperature oxidation chemistry of dimethyl ether (DME) from 400 K to 750 K has been investigated in the mixture of DME/O 3/O 2/He/Ar in an atmospheric-pressure flow reactor coupled with the molecular beam mass spectrometry (MBMS) sampling technique. The mole fraction of ozone was varied from 0 to 0.146% in the mixture to study its enhanced kinetic effect on DME oxidation. The mole fractions of DME, O 2, O 3, CH 2 O, H 2 O 2, CO, CO 2, and CH 3 OCHO were quantified as functions of temperature at …
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researchgate.net 参考文章(27)
Yiguang Ju, Christopher B. Reuter, Sang Hee Won, Numerical simulations of premixed cool flames of dimethyl ether/oxygen mixtures Combustion and Flame. ,vol. 162, pp. 3580- 3588 ,(2015) , 10.1016/J.COMBUSTFLAME.2015.06.014
R. D. Naylor, S. P. Kirby, J. B. Pedley, Thermochemical data of organic compounds ,(1986)
R.J. Morrissey, C.C.S.J. Schubert, The reactions of ozone with propane and ethane Combustion and Flame. ,vol. 7, pp. 263- 268 ,(1963) , 10.1016/0010-2180(63)90191-3
H. J. Curran, W. J. Pitz, C. K. Westbrook, P. Dagaut, J-C Boettner, M. Cathonnet, A WIDE RANGE MODELING STUDY OF DIMETHYL ETHER OXIDATION International Journal of Chemical Kinetics. ,vol. 30, pp. 229- 241 ,(1998) , 10.1002/(SICI)1097-4601(1998)30:3<229::AID-KIN9>3.0.CO;2-U
Friederike Herrmann, Kai Moshammer, Fei Qi, Katharina Kohse-Höinghaus, Zhandong Wang, Xiaoyuan Zhang, Lili Xing, Lidong Zhang, Experimental and kinetic modeling study of the low- and intermediate-temperature oxidation of dimethyl ether Combustion and Flame. ,vol. 162, pp. 1113- 1125 ,(2015) , 10.1016/J.COMBUSTFLAME.2014.10.003
Philippe Dagaut, Jean-Claude Boettner, Michel Cathonnet, Chemical kinetic study of dimethylether oxidation in a jet stirred reactor from 1 to 10 ATM: Experiments and kinetic modeling Symposium (International) on Combustion. ,vol. 26, pp. 627- 632 ,(1996) , 10.1016/S0082-0784(96)80269-4
Clarence C. Schubert, S.J. Schubert, Robert N. Pease, The Oxidation of Lower Paraffin Hydrocarbons. I. Room Temperature Reaction of Methane, Propane, n-Butane and Isobutane with Ozonized Oxygen1 Journal of the American Chemical Society. ,vol. 78, pp. 2044- 2048 ,(1956) , 10.1021/JA01591A006
S. L. Fischer, F. L. Dryer, H. J. Curran, The reaction kinetics of dimethyl ether. I: High‐temperature pyrolysis and oxidation in flow reactors International Journal of Chemical Kinetics. ,vol. 32, pp. 713- 740 ,(2000) , 10.1002/1097-4601(2000)32:12<713::AID-KIN1>3.0.CO;2-9
U. Pfahl, K. Fieweger, G. Adomeit, Self-ignition of diesel-relevant hydrocarbon-air mixtures under engine conditions Symposium (International) on Combustion. ,vol. 26, pp. 781- 789 ,(1996) , 10.1016/S0082-0784(96)80287-6
Wenting Sun, Sang Hee Won, Yiguang Ju, In situ plasma activated low temperature chemistry and the S-curve transition in DME/oxygen/helium mixture Combustion and Flame. ,vol. 161, pp. 2054- 2063 ,(2014) , 10.1016/J.COMBUSTFLAME.2014.01.028