A comparative study on the magnetic properties of MFe12O19 and MAlFe11O19 (M=Sr, Ba and Pb) hexaferrites with different morphologies

作者: Sonal Singhal , Tsering Namgyal , Jagdish Singh , Kailash Chandra , Sandeep Bansal

DOI: 10.1016/J.CERAMINT.2011.02.001

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摘要: Abstract M-type nano hexaferrites MFe 12 O 19 and MAlFe 11 (M = Sr, Ba Pb) have been prepared by the sol–gel method to investigate shielding effect of inorganic ions KCl, KBr KI on phase growth ferrites. FTIR frequency bands in range 560–580 cm −1 430–470 cm corresponds formation tetrahedral octahedral clusters metal oxides ferrites, respectively. X-ray powder diffractographs do not show any peaks for as obtained samples showing amorphous nature samples, however regular structure all annealed samples. There is negligible small change lattice parameters ‘ a ’ c with substitution hexagonal ferrites aluminium. Magnetic measurements showed that coercivity (Hc) values KCl enhance due act deactivators. However, value decreases it oxidise I 2 during annealing. The saturation magnetization Al 3+ ion Fe preferential occupancy aluminium sites.

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