Protic Ruthenium Tris(pyrazol-3-ylmethyl)amine Complexes Featuring a Hydrogen-Bonding Network in the Second Coordination Sphere
作者： Hiroaki Yamagishi , Shohei Nabeya , Takao Ikariya , Shigeki Kuwata
DOI: 10.1021/ACS.INORGCHEM.5B02044
关键词:
摘要: We synthesized ruthenium complexes bearing a tris(pyrazol-3-ylmethyl)amine ligand LH3 and revealed that this tripodal allows predictable accumulation of three proton-delivering NH groups around coordination site. The Bronsted acidity the in led to formation multiple hydrogen bonds with substrate deprotonation. chlorido complex ligated by catalyzed disproportionation 1,2-diphenylhydrazine.
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