Structure and biosynthesis of 5-deoxyfusarubin and anhydro-5-deoxyfusarubin, naphthaquinone pigments from Nectria haematococca

作者: Denise Parisot , Michel Devys , Michel Barbier

DOI: 10.1016/S0031-9422(00)83104-0

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摘要: Abstract Two naphthaquinone pigments, 5-deoxyfusarubin and anhydro-5-deoxyfusarubin, were isolated from a yellow strain of the fungus Nectria haematococca. The 13C NMR spectra 2 biosynthetically labelled [1-13C]acetate confirmed structures pigments established heptaketide origin molecules.

参考文章(10)
James H. Tatum, Robert A. Baker, Naphthoquinones produced by Fusarium solani isolated from citrus Phytochemistry. ,vol. 22, pp. 543- 547 ,(1983) , 10.1016/0031-9422(83)83042-8
Denise Parisot, Michel Devys, Jean-Pierre Férézou, Michel Barbier, Pigments from Nectria haematococca: Anhydrofusarubin lactone and nectriafurone Phytochemistry. ,vol. 22, pp. 1301- 1303 ,(1983) , 10.1016/0031-9422(83)80253-2
Itsuo Kurobane, Leo C. Vining, A. Gavin McInnes, Donald G. Smith, Diastereoisomeric 4a,10a-dihydrofusarubins: True metabolites of Fusarium solani Canadian Journal of Chemistry. ,vol. 56, pp. 1593- 1594 ,(1978) , 10.1139/V78-260
Itsuo Kurobane, Leo C. Vining, A. Gavin McInnes, John A. Walter, Use of 13C in biosynthetic studies. The labeling pattern in dihydrofusarubin enriched from [13C]- and [13C, 2H]acetate in cultures of Fusarium solani Canadian Journal of Chemistry. ,vol. 58, pp. 1380- 1385 ,(1980) , 10.1139/V80-217
A. Stoessl, Some metabolites of Alternariasolani Canadian Journal of Chemistry. ,vol. 47, pp. 767- 776 ,(1969) , 10.1139/V69-125
D. Parisot, M. Maugin, C. Gerlinger, Genes Controlling Pigmentation in Nectria haematococca Microbiology. ,vol. 130, pp. 1543- 1555 ,(1984) , 10.1099/00221287-130-6-1543
ANNA MARIA BECKER, RODNEY W. RICKARDS, KARL J. SCHMALZL, Ho C. YICK, Metabolites of Dactylaria lutea. The structures of dactylariol and the antiprotozoal antibiotic dactylarin. The Journal of Antibiotics. ,vol. 31, pp. 324- 329 ,(1978) , 10.7164/ANTIBIOTICS.31.324
A. Arnone, G. Cardillo, L. Merlini, R. Mondelli, NMR effects of acetylation and long-range coupling as a tool for structural elucidation of hydroxychromenes Tetrahedron Letters. ,vol. 8, pp. 4201- 4206 ,(1967) , 10.1016/S0040-4039(00)72996-0