Specific approaches to dramatic reduction in stack activation time and perfect long-term storage for high-performance air-breathing polymer electrolyte membrane fuel cell

作者: Seung Yong Yang , Dong-Jun Seo , Myeong-Ri Kim , Won-Young Choi , Young-Gi Yoon

DOI: 10.1016/J.IJHYDENE.2017.05.119

关键词:

摘要: Abstract Air-breathing polymer electrolyte membrane fuel cell (PEMFC) systems without the humidifier and air blower have been developed to overcome cost complexity of balance plants (BOPs). Until now, there has no specific way improve stack's initial performance through activation protocol maintain for a very long time. Herein, we studied technique finishing total within 1 h by using pre-activation process (i.e., soaking stack in DI-water reservoir) applying current at 0.65 V. The procedure significantly increased swelling Nafion binder catalyst layer, reducing Also, showed that long-term storage humidified N 2 gas closed box did not hinder electrocatalytic activity Pt drying 60 days.

参考文章(32)
Quentin Meyer, Ahmed Himeur, Sean Ashton, Oliver Curnick, Ralph Clague, Tobias Reisch, Paul Adcock, Paul R. Shearing, Daniel J.L. Brett, System-level electro-thermal optimisation of air-cooled open-cathode polymer electrolyte fuel cells: Air blower parasitic load and schemes for dynamic operation International Journal of Hydrogen Energy. ,vol. 40, pp. 16760- 16766 ,(2015) , 10.1016/J.IJHYDENE.2015.07.040
Oluwamayowa A. Obeisun, Quentin Meyer, Erik Engebretsen, Donal P. Finegan, James B. Robinson, Gareth Hinds, Paul R. Shearing, Daniel J.L. Brett, Study of water accumulation dynamics in the channels of an open-cathode fuel cell through electro-thermal characterisation and droplet visualisation International Journal of Hydrogen Energy. ,vol. 40, pp. 16786- 16796 ,(2015) , 10.1016/J.IJHYDENE.2015.07.066
Jae Yeong Cheon, Taeyoung Kim, YongMan Choi, Hu Young Jeong, Min Gyu Kim, Young Jin Sa, Jaesik Kim, Zonghoon Lee, Tae-Hyun Yang, Kyungjung Kwon, Osamu Terasaki, Gu-Gon Park, Radoslav R. Adzic, Sang Hoon Joo, Ordered mesoporous porphyrinic carbons with very high electrocatalytic activity for the oxygen reduction reaction Scientific Reports. ,vol. 3, pp. 2715- 2715 ,(2013) , 10.1038/SREP02715
Zi'ang Xiong, Shijun Liao, Dai Dang, Xinlong Tian, Sanying Hou, Fangfang Liu, Hongliang Peng, Zhiyong Fu, Enhanced water management in the cathode of an air-breathing PEMFC using a dual catalyst layer and optimizing the gas diffusion and microporous layers International Journal of Hydrogen Energy. ,vol. 40, pp. 3961- 3967 ,(2015) , 10.1016/J.IJHYDENE.2015.01.091
Angel A. Topalov, Serhiy Cherevko, Aleksandar R. Zeradjanin, Josef C. Meier, Ioannis Katsounaros, Karl J. J. Mayrhofer, Towards a comprehensive understanding of platinum dissolution in acidic media Chemical Science. ,vol. 5, pp. 631- 638 ,(2014) , 10.1039/C3SC52411F
Jinfeng Wu, Stefano Galli, Ivano Lagana, Afonso Pozio, Giulia Monteleone, Xiao Zi Yuan, Jonathan Martin, Haijiang Wang, An air-cooled proton exchange membrane fuel cell with combined oxidant and coolant flow Journal of Power Sources. ,vol. 188, pp. 199- 204 ,(2009) , 10.1016/J.JPOWSOUR.2008.11.078
Taeyoung Kim, Seungjae Lee, Heekyung Park, A study of water transport as a function of the micro-porous layer arrangement in PEMFCs International Journal of Hydrogen Energy. ,vol. 35, pp. 8631- 8643 ,(2010) , 10.1016/J.IJHYDENE.2010.05.123
Sun-Mi Hwang, Jae-Hyun Park, Seongyop Lim, Doo-Hwan Jung, Hwanuk Guim, Young-Gi Yoon, Sung-Dae Yim, Tae-Young Kim, Designing an ultrathin silica layer for highly durable carbon nanofibers as the carbon support in polymer electrolyte fuel cells Nanoscale. ,vol. 6, pp. 12111- 12119 ,(2014) , 10.1039/C4NR04293J