High-Nitrogen Compounds For Use in Low-Erosivity Gun Propellants

摘要: Abstract : Nitrogen rich compounds are suitable as ingredients in low smoke propellant charges. Several high-N energetic materials presented which based on tetrazoles. Tetrazoles an unique class of compounds, since they combine a high nitrogen content and heat formation with good thermal kinetic stabilities due to their aromatic ring system. The reaction 5-azidotetrazole hydrazine yields hydrazinium 5-azidotetrazolate (1), is the tetrazole salt highest (88.1 %) reported, yet. In addition ammonium aminoguanidinium 5-azidoterazolate were synthesized characterized. detonation propulsion parameter calculated using EXPLO5 program. several outperforming derivatives (N% > 80 %), currently under our investigation additives charges, presented. Using heats X-ray densities, 5-aminotetrazole, 5,5'- bis(1H-tetrazolyl)-hydrazine, 5,5'-bis(1H-tetrazolyl)- amine, 5,5'-bis(1-methyltetrazolyl)-triazene, 1,5-bistetrazole its calculated.