Process for the production of low color 2,3-epoxypropyl trialkylammonium halide

作者: Dorothy L. Roerden , Laren P. Childers

DOI:

关键词:

摘要: An aqueous solution of 2,3-Epoxypropyltrimethylammonium chloride having reduced color and method preparation are disclosed. is treated with sodium hypochlorite to reduce its color. 2-3-Epoxypropyltrimethylammonium can be prepared via reaction trimethylamine epichlorohydrin. If desired, an aprotic solvent used. formed in the resultant slurry, must then isolated known methods, such as evaporation, extraction, centrifugation, etc. depending upon other constituents slurry residual epichlorohydrin removed. The final product effective amount hypochlorite. obtained used for, for example, color-sensitive applications produce cationic starch use paper manufacture.

参考文章(10)
Russell T Mcfadden, Ralph R Langher, John C Walling, Synthesis of 3-chloro-2-hydroxypropyl quaternary ammonium salts ,(1967)
Joseph B. Doughty, Robert E. Klem, Process for making quaternary amines of epichlorohydrin ,(1974)
Robert J Hathaway, Paul R Shildneck, Preparation of quaternary ammonium starch ethers ,(1964)
James D. McClure, Glycidyltrimethylammonium chloride and related compounds Journal of Organic Chemistry. ,vol. 35, pp. 2059- 2061 ,(1970) , 10.1021/JO00831A093
David M. Hall, John D. Kitchens, Robert T. Patton, Process for improving the dyeability and whiteness of cellulosic fabrics ,(1989)
James D Mcclure, Paul H Williams, Production of epoxy ammonium salts ,(1967)
Wolfgang Fischer, Gert Roessler, Manfred Langer, Production of 2, 3-epoxypropyl trialkyl ammonium chlorides ,(1995)