Low-temperature specific heat of C60.

作者: W. P. Beyermann , M. F. Hundley , J. D. Thompson , F. N. Diederich , G. Grüner

DOI: 10.1103/PHYSREVLETT.68.2046

关键词:

摘要: We have measured a large specific heat of polycrystalline ${\mathrm{C}}_{60}$ from T=1.4 to 20 K. The data were adequately fitted by model containing Debye terms, Einstein oscillators, and linear contribution. An analysis incorporating both vibrational strongly coupled rotational degrees freedom expected for the simple-cubic structure at low temperatures is proposed. also discuss possible interpretation based on fairly narrow feature in excitation spectrum. term may be consequence disorder resulting distribution two-level tunneling centers.

参考文章(17)
W. Krätschmer, Lowell D. Lamb, K. Fostiropoulos, Donald R. Huffman, Solid C60: a new form of carbon Nature. ,vol. 347, pp. 354- 358 ,(1990) , 10.1038/347354A0
Donald S. Bethune, Gerard Meijer, Wade C. Tang, Hal J. Rosen, William G. Golden, Hajime Seki, Charles A. Brown, Mattanjah S. de Vries, Vibrational Raman and infrared spectra of chromatographically separated C60 and C70 fullerene clusters Chemical Physics Letters. ,vol. 179, pp. 181- 186 ,(1991) , 10.1016/0009-2614(91)90312-W
R. L. Cappelletti, J. R. D. Copley, W. A. Kamitakahara, Fang Li, J. S. Lannin, D. Ramage, NEUTRON MEASUREMENTS OF INTRAMOLECULAR VIBRATIONAL MODES IN C60 Physical Review Letters. ,vol. 66, pp. 3261- 3264 ,(1991) , 10.1103/PHYSREVLETT.66.3261
C. S. Yannoni, R. D. Johnson, G. Meijer, D. S. Bethune, J. R. Salem, Carbon-13 NMR study of the C60 cluster in the solid state: molecular motion and carbon chemical shift anisotropy The Journal of Physical Chemistry. ,vol. 95, pp. 9- 10 ,(1991) , 10.1021/J100154A005
R. Tycko, R. C. Haddon, G. Dabbagh, S. H. Glarum, D. C. Douglass, A. M. Mujsce, Solid-state magnetic resonance spectroscopy of fullerenes The Journal of Physical Chemistry. ,vol. 95, pp. 518- 520 ,(1991) , 10.1021/J100155A006
Paul A. Heiney, John E. Fischer, Andrew R. McGhie, William J. Romanow, Arnold M. Denenstein, John P. McCauley Jr., Amos B. Smith, David E. Cox, Orientational ordering transition in solid C 60 Physical Review Letters. ,vol. 66, pp. 2911- 2914 ,(1991) , 10.1103/PHYSREVLETT.66.2911
Henry. Ajie, Marcos M. Alvarez, Samir J. Anz, Rainer D. Beck, Francois. Diederich, K. Fostiropoulos, Donald R. Huffman, Wolfgang. Kraetschmer, Yves. Rubin, . et al., Characterization of the soluble all-carbon molecules C60 and C70 The Journal of Physical Chemistry. ,vol. 94, pp. 8630- 8633 ,(1990) , 10.1021/J100387A004
Peter W. Stephens, Laszlo Mihaly, Peter L. Lee, Robert L. Whetten, Shiou-Mei Huang, Richard Kaner, François Deiderich, Karoly Holczer, Structure of single-phase superconducting K3C60 Nature. ,vol. 351, pp. 632- 634 ,(1991) , 10.1038/351632A0
Stanford University. Microwave Laboratory, Heat Capacity Measurements on Small Samples at Low Temperatures Review of Scientific Instruments. ,vol. 43, pp. 205- 214 ,(1972) , 10.1063/1.1685596
W. Desorbo, G.E. Nichols, A calorimeter for the temperature region 1–20°K—The specific heat of some graphite specimens Journal of Physics and Chemistry of Solids. ,vol. 6, pp. 352- 366 ,(1958) , 10.1016/0022-3697(58)90054-4