Syntheses and characterizations of tetracyanoplatinate(II) complexes with 2-pyridineethanol
作者： Elvan Sayin , Güneş Süheyla Kürkçüoğlu , Okan Zafer Yeşilel , Tuncer Hökelek
DOI: 10.1080/00958972.2015.1048239
关键词:
摘要: The cyanide-bridged heteronuclear polymeric complexes, [M(hepH)2Pt(μ-CN)2(CN)2]n (M = Cu(II) (1), Zn(II) (2) and Cd(II) (3); hepH = 2-pyridineethanol), have been synthesized characterized by elemental analysis, FT-IR Raman spectroscopies, thermal single-crystal X-ray diffraction techniques. crystallographic analyses reveal that 1 2 crystallize in the triclinic system, space group P-1, while 3 crystallizes monoclinic P21/n. structures of 1–3 consist 1-D linear chains which M(II) Pt(II) ions are linked cyanide ligands. Each center exhibits a distorted octahedral coordination environment with four nitrogens from two cyanides hepH further C–H⋯Pt O–H⋯N hydrogen bonding interactions to construct 3-D supramolecular structures. Thermal stabilities decomposition products complexes were investigated 30 700 °C air.
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