Osmium(III) and Osmium(IV) complexes of bi- and polydentate thioethers
作者： Rusmidah Ali , Simon J. Higgins , William Levason
DOI: 10.1016/S0020-1693(00)87670-7
关键词:
摘要: Osmium(III) complexes of the dithioethers (LL) PhS(CH2)2SPh, cis-PhSCHCHSPh, MeS(Ch2)2SMe, cis-MeSCHCHSMe and o-C6H4(SMe)2 type Os(LL)1.5X3 (X = Cl, Br) have been prepared from Na2OsX6 excess LL in 2-ethoxyethanol. The trithioether S(CH2CH2CH2SMe)2(L3) produces both OsIV [OsL3X4] OsIII mer[OsL3X3] complexes. New [OsLnCl4] (Ln CH3C(CH2SMe)3, S(CH2)2S(CH2)3S(CH2)2S(CH2)3), mer-[Ru(S(CH2CH2CH2SMe)2)Cl3] fac-[Ru(S(CH2)2S(CH2)3S(CH2)2S(CH2)3)X3] are described. were charcterised by IR, electronic EPR spectra magnetic measurements.
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