A stable Li-deficient oxide as high-performance cathode for advanced lithium-ion batteries
作者： Peiyu Hou , Jie Wang , Jishun Song , Dawei Song , Xixi Shi
DOI: 10.1039/C4CC09344E
关键词:
摘要: Monodisperse Li-deficient Li0.35Ni0.2Co0.1Mn0.7O2−x spinel single crystals have been prepared for the first time. The oxide surprisingly delivers large reversible capacity (251.3 mA h g−1), outstanding cycle life and low median-voltage of 2.7 V in range 2.0–4.9 V. Importantly, high (4.4 V) superior rate capability are also obtained from 3.0 to 5.0 These results indicate that high-energy or high-power density can be achieved by controlling discharge cut-off voltage.
rsc.org
sci-hub.se 参考文章(41)
Qiming Zhong, Arman Bonakdarpour, Meijie Zhang, Yuan Gao, J. R. Dahn, Synthesis and Electrochemistry of LiNi x Mn2 − x O 4 Journal of The Electrochemical Society. ,vol. 144, pp. 205- 213 ,(1997) , 10.1149/1.1837386
Anthony W. Moses, Harry G. Garcia Flores, Jong-Gyu Kim, Marjorie A. Langell, Surface properties of LiCoO2, LiNiO2 and LiNi1−xCoxO2 Applied Surface Science. ,vol. 253, pp. 4782- 4791 ,(2007) , 10.1016/J.APSUSC.2006.10.044
Naoaki Yabuuchi, Kazuhiro Yoshii, Seung-Taek Myung, Izumi Nakai, Shinichi Komaba, Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li2MnO3−LiCo1/3Ni1/3Mn1/3O2 Journal of the American Chemical Society. ,vol. 133, pp. 4404- 4419 ,(2011) , 10.1021/JA108588Y
Dapeng Wang, Ilias Belharouak, Guangwen Zhou, Khalil Amine, None, Nanoarchitecture Multi-Structural Cathode Materials for High Capacity Lithium Batteries Advanced Functional Materials. ,vol. 23, pp. 1070- 1075 ,(2013) , 10.1002/ADFM.201200536
M.M. Thackeray, W.I.F. David, P.G. Bruce, J.B. Goodenough, Lithium insertion into manganese spinels Materials Research Bulletin. ,vol. 18, pp. 461- 472 ,(1983) , 10.1016/0025-5408(83)90138-1
A. Robert Armstrong, Michael Holzapfel, Petr Novák, Christopher S. Johnson, Sun-Ho Kang, Michael M. Thackeray, Peter G. Bruce, Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 Journal of the American Chemical Society. ,vol. 128, pp. 8694- 8698 ,(2006) , 10.1021/JA062027+
A. N. Mansour, C. A. Melendres, Characterization of Ni2O3⋅6H2O by XPS Surface Science Spectra. ,vol. 3, pp. 263- 270 ,(1994) , 10.1116/1.1247755
Qiliang Wei, Xianyou Wang, Xiukang Yang, Bowei Ju, Benan Hu, Hongbo Shu, Weicheng Wen, Meng Zhou, Yunfeng Song, Hao Wu, Hai Hu, Spherical concentration-gradient LiMn1.87Ni0.13O4 spinel as a high performance cathode for lithium ion batteries Journal of Materials Chemistry. ,vol. 1, pp. 4010- 4016 ,(2013) , 10.1039/C3TA01698F
Michael A. Stranick, Mn2O3 by XPS Surface Science Spectra. ,vol. 6, pp. 39- 46 ,(1999) , 10.1116/1.1247889
Peiyu Hou, Xiaoqing Wang, Dongge Wang, Dawei Song, Xixi Shi, Lianqi Zhang, Jian Guo, Jun Zhang, A novel core-concentration gradient-shelled LiNi0.5Co0.2Mn0.3O2as high-performance cathode for lithium-ion batteries RSC Advances. ,vol. 4, pp. 15923- 15929 ,(2014) , 10.1039/C3RA47930G