Chlorination of Low-Band-Gap Polymers: Toward High-Performance Polymer Solar Cells
作者： Daize Mo , Huan Wang , Hui Chen , Shiwei Qu , Pengjie Chao
DOI: 10.1021/ACS.CHEMMATER.6B04828
关键词:
摘要: Halogenation is an effective way to tune the energy levels of organic semiconducting materials. To date, fluorination materials fabricate polymer solar cells (PSCs) has been used far more than chlorination; however, fluorine exchange reactions suffer from low yields and resulting fluorinated always comes with a higher price, which will greatly hinder their commercial applications. Herein, we designed synthesized series chlorinated donor–acceptor (D-A) type polymers, in benzo[1,2-b:4,5-b]dithiophene benzothiadiazole units are connected by thiophene π-bridges asymmetric alkyl chain. These polymers showed deep highest occupied molecular orbital (HOMO) levels, promoted efficiency corresponding PSCs increasing device open circuit voltage. The chain on moieties gave final sufficient solubility for solution processing strong π–π stacking fi...
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sci-hub.se 参考文章(51)
Xiaochen Wang, Pei Jiang, Yu Chen, Hao Luo, Zhiguo Zhang, Haiqiao Wang, Xiaoyu Li, Gui Yu, Yongfang Li, Thieno[3,2-b]thiophene-Bridged D-π-A Polymer Semiconductor Based on Benzo[1,2-b:4,5-b']dithiophene and Benzoxadiazole Macromolecules. ,vol. 46, pp. 4805- 4812 ,(2013) , 10.1021/MA4005555
Mei Gao, Jegadesan Subbiah, Paul B Geraghty, Ming Chen, Balaji Purushothaman, Xiwen Chen, Tianshi Qin, Doojin Vak, Fiona H Scholes, Scott E Watkins, Melissa Skidmore, Gerard J Wilson, Andrew B Holmes, David J Jones, Wallace WH Wong, None, Development of a High-Performance Donor Acceptor Conjugated Polymer: Synergy in Materials and Device Optimization Chemistry of Materials. ,vol. 28, pp. 3481- 3487 ,(2016) , 10.1021/ACS.CHEMMATER.6B01194
Huifeng Yao, Hao Zhang, Long Ye, Wenchao Zhao, Shaoqing Zhang, Jianhui Hou, Molecular Design and Application of a Photovoltaic Polymer with Improved Optical Properties and Molecular Energy Levels Macromolecules. ,vol. 48, pp. 3493- 3499 ,(2015) , 10.1021/ACS.MACROMOL.5B00649
Sunsun Li, Long Ye, Wenchao Zhao, Shaoqing Zhang, Subhrangsu Mukherjee, Harald Ade, Jianhui Hou, Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells Advanced Materials. ,vol. 28, pp. 9423- 9429 ,(2016) , 10.1002/ADMA.201602776
In Hwan Jung, Donglin Zhao, Jaeyoung Jang, Wei Chen, Erik S. Landry, Luyao Lu, Dmitri V. Talapin, Luping Yu, Development and Structure/Property Relationship of New Electron Accepting Polymers Based on Thieno[2′,3′:4,5]pyrido[2,3-g]thieno[3,2-c]quinoline-4,10-dione for All-Polymer Solar Cells Chemistry of Materials. ,vol. 27, pp. 5941- 5948 ,(2015) , 10.1021/ACS.CHEMMATER.5B01928
Jae Kwan Lee, Wan Li Ma, Christoph J. Brabec, Jonathan Yuen, Ji Sun Moon, Jin Young Kim, Kwanghee Lee, Guillermo C. Bazan, Alan J. Heeger, Processing Additives for Improved Efficiency from Bulk Heterojunction Solar Cells Journal of the American Chemical Society. ,vol. 130, pp. 3619- 3623 ,(2008) , 10.1021/JA710079W
Qiang Peng, Xiangju Liu, Dan Su, Guanwen Fu, Jun Xu, Liming Dai, Novel Benzo[1,2‐b:4,5‐b′]dithiophene–Benzothiadiazole Derivatives with Variable Side Chains for High‐Performance Solar Cells Advanced Materials. ,vol. 23, pp. 4554- 4558 ,(2011) , 10.1002/ADMA.201101933
Ted M Pappenfus, Deborah K Schneiderman, Juan Casado, Juan T Lopez Navarrete, M Carmen Ruiz Delgado, Gianni Zotti, Barbara Vercelli, Matthew D Lovander, Lindsay M Hinkle, Jon N Bohnsack, Kent R Mann, None, Oligothiophene Tetracyanobutadienes: Alternative Donor−Acceptor Architectures for Molecular and Polymeric Materials† Chemistry of Materials. ,vol. 23, pp. 823- 831 ,(2011) , 10.1021/CM102128G
Pavel Schilinsky, Christoph Waldauf, Jens Hauch, Christoph J. Brabec, Simulation of light intensity dependent current characteristics of polymer solar cells Journal of Applied Physics. ,vol. 95, pp. 2816- 2819 ,(2004) , 10.1063/1.1646435
W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology Advanced Functional Materials. ,vol. 15, pp. 1617- 1622 ,(2005) , 10.1002/ADFM.200500211