An efficient platform based on strontium titanate nanocubes interleaved polypyrrole nanohybrid as counter electrode for dye-sensitized solar cell

作者: Usman Ahmed , M.M. Shahid , Syed Shahabuddin , Nasrudin Abd Rahim , Mahdi Alizadeh

DOI: 10.1016/J.JALLCOM.2020.158228

关键词:

摘要: Abstract In the present work, we have synthesized polypyrrole incorporated with SrTiO3 nanoparticles by oxidative polymerization method. The prepared samples were thoroughly characterized various instrumental methods for crystallinity and crystal structure, chemical bonding, optical nature, morphology, elemental composition, etc. X-ray diffraction (XRD) patterns showed highly crystalline nanoparticle. With addition of in PPy, a PPy-SrTiO3 nanocomposite was achieved. Moreover, this confirms formation evenly distributed nanoparticle-polymer interaction. FESEM images revealed that PPy exhibited nanosphere morphology. Further, nanocubes it shows high SrTiO3. mapping show details about distribution into polymeric chain PPy. EDX spectrum indicated presence C, Ti, O, Sr, N, Si nanocomposite. successful composites properties confirmed FTIR UV–Vis spectroscopic analysis. evolution electronic circuits optoelectronic devices, is crucially significant but remains challenging to fabricate new electrode switches traditional platinum (Pt) indium counter electrodes dye-sensitized solar cells (DSSCs). These conventionally used exhibit noticeable cons such as instability, cost, complex fabrication when DSSCs. Therefore, unaided DSSC very low efficiency 1.29%. However, incorporation poly matrix enhanced surface area, electrocatalytic response towards redox system, also charge transfer resistance. Among other concentrations, PPy-SrTiO3-50% achieved power conversion 2.52% which higher than sputtered Pt i.e. 2.17%.

参考文章(64)
Qingquan He, Tianyue Qian, Jiantao Zai, Qiquan Qiao, Shoushuang Huang, Yiran Li, Min Wang, Efficient Ag8GeS6 counter electrode prepared from nanocrystal ink for dye-sensitized solar cells Journal of Materials Chemistry. ,vol. 3, pp. 20359- 20365 ,(2015) , 10.1039/C5TA05304H
Shengjie Peng, Lingling Tian, Jing Liang, Subodh G. Mhaisalkar, Seeram Ramakrishna, Polypyrrole Nanorod Networks/Carbon Nanoparticles Composite Counter Electrodes for High-Efficiency Dye-Sensitized Solar Cells ACS Applied Materials & Interfaces. ,vol. 4, pp. 397- 404 ,(2012) , 10.1021/AM201461C
Alex Aboagye, Hytham Elbohy, Ajit D. Kelkar, Qiquan Qiao, Jiantao Zai, Xuefeng Qian, Lifeng Zhang, Electrospun carbon nanofibers with surface-attached platinum nanoparticles as cost-effective and efficient counter electrode for dye-sensitized solar cells Nano Energy. ,vol. 11, pp. 550- 556 ,(2015) , 10.1016/J.NANOEN.2014.10.033
Kouichi Nakashima, Masatoshi Kera, Ichiro Fujii, Satoshi Wada, A new approach for the preparation of SrTiO3 nanocubes Ceramics International. ,vol. 39, pp. 3231- 3234 ,(2013) , 10.1016/J.CERAMINT.2012.10.009
Sadia Ameen, M Shaheer Akhtar, Young Soon Kim, O-Bong Yang, Hyung-Shik Shin, None, Sulfamic Acid-Doped Polyaniline Nanofibers Thin Film-Based Counter Electrode: Application in Dye-Sensitized Solar Cells Journal of Physical Chemistry C. ,vol. 114, pp. 4760- 4764 ,(2010) , 10.1021/JP912037W
N. Papageorgiou, P. Liska, A. Kay, M. Grätzel, Mediator Transport in Multilayer Nanocrystalline Photoelectrochemical Cell Configurations Journal of The Electrochemical Society. ,vol. 146, pp. 898- 907 ,(1999) , 10.1149/1.1391698
Jiangbin Xia, Ling Chen, Shozo Yanagida, Application of polypyrrole as a counter electrode for a dye-sensitized solar cell Journal of Materials Chemistry. ,vol. 21, pp. 4644- 4649 ,(2011) , 10.1039/C0JM04116E
Jiangbin Xia, Naruhiko Masaki, Kejian Jiang, Shozo Yanagida, The influence of doping ions on poly(3,4-ethylenedioxythiophene) as a counter electrode of a dye-sensitized solar cell Journal of Materials Chemistry. ,vol. 17, pp. 2845- 2850 ,(2007) , 10.1039/B703062B
Takurou N. Murakami, Seigo Ito, Qing Wang, Md. Khaja Nazeeruddin, Takeru Bessho, Ilkay Cesar, Paul Liska, Robin Humphry-Baker, Pascal Comte, Péter Péchy, Michael Grätzel, Highly Efficient Dye-Sensitized Solar Cells Based on Carbon Black Counter Electrodes Journal of The Electrochemical Society. ,vol. 153, ,(2006) , 10.1149/1.2358087
Enbing Bi, Han Chen, Xudong Yang, Wenqin Peng, Michael Grätzel, Liyuan Han, A quasi core–shell nitrogen-doped graphene/cobalt sulfide conductive catalyst for highly efficient dye-sensitized solar cells Energy and Environmental Science. ,vol. 7, pp. 2637- 2641 ,(2014) , 10.1039/C4EE01339E