Polymer supported iron catalysts for the oxidation of cyclohexane

作者: Ki-Won Jun , Eun-Kyung Shim , Seong-Bo Kim , Kyu-Wan Lee

DOI: 10.1016/S0167-2991(08)63461-8

关键词:

摘要: Catalytic oxidation of cyclohexane was studied under the mild condition by using hydrogen peroxide formed from molecular and oxygen in original place. Iron chlorides were immobilized on poly (4-vinylpyridine) cross-linked with divinylbenzene could be used successfully as catalysts.

参考文章(17)
Vera S. Belova, Alexander M. Khenkin, Victor N. Postnov, Valerii E. Prusakov, Alexander E. Shilov, Marina L. Stepanova, Oxidation of Alkanes by Dioxygen in the Presence of an Iron Complex immobilized on Modified Silica. Chemical Model of Methane Monooxygenase Mendeleev Communications. ,vol. 2, pp. 7- 8 ,(1992) , 10.1070/MC1992V002N01ABEH000095
Norman Herron, Galen D. Stucky, Chadwick A. Tolman, Shape selectivity in hydrocarbon oxidations using zeolite encapsulated iron phthalocyanine catalysts Journal of The Chemical Society, Chemical Communications. pp. 1521- 1522 ,(1986) , 10.1039/C39860001521
Ki-Won Jun, Kyu-Wan Lee, Hydroxylierung von Cyclohexan mit H2 und O2 in Aceton an Fe‐Pd/SiO2‐Katalysatoren Chemie Ingenieur Technik. ,vol. 64, pp. 637- 639 ,(1992) , 10.1002/CITE.330640713
Takashi Tatsumi, Makoto Nakamura, Hiro-o Tominaga, Hydroxylation of alkanes catalyzed by manganese tetraphenylporphyrin immobilized on imidazole-modified silica gel Catalysis Today. ,vol. 6, pp. 163- 170 ,(1989) , 10.1016/0920-5861(89)85019-9
Chris Bowers, Prabir K Dutta, Olefin oxidation by zeolite-encapsulated Mn(salen)+ complexes under ambient conditions Journal of Catalysis. ,vol. 122, pp. 271- 279 ,(1990) , 10.1016/0021-9517(90)90281-N
Robert H. Crabtree, The organometallic chemistry of alkanes Chemical Reviews. ,vol. 17, pp. 245- 269 ,(1985) , 10.1021/CR00068A002
Norman Herron, Chadwick A. Tolman, A highly selective zeolite catalyst for hydrocarbon oxidation. A completely inorganic mimic of the alkane .omega.-hydroxylases Journal of the American Chemical Society. ,vol. 109, pp. 2837- 2839 ,(1987) , 10.1021/JA00243A054
Laurent Barloy, Pierrette Battioni, Daniel Mansuy, Manganese porphyrins supported on montmorillonite as hydrocarbon mono-oxygenation catalysts: particular efficacy for linear alkane hydroxylation Journal of The Chemical Society, Chemical Communications. pp. 1365- 1367 ,(1990) , 10.1039/C39900001365
Ki-Won Jun, Kyu-Wan Lee, Eun-Kyung Shim, Nam-Sook Cho, Selective oxidation of cyclohexane by an iron-palladium bicatalytic system under mild conditions; iron oxide/silica catalysts Applied Catalysis A-general. ,vol. 96, pp. 269- 278 ,(1993) , 10.1016/0926-860X(90)80015-7