Enhanced red emission in ZnB2O4:Eu3+ by charge compensation

作者: Zhongfei Mu , Yihua Hu , Li Chen , Xiaojuan Wang

DOI: 10.1016/J.OPTMAT.2011.07.012

关键词:

摘要: Abstract Eu 3+ doped ZnB 2 O 4 without or with different charge compensation (CC) approaches (co-doping Li + , Na K, decreasing the content of Zn 2+ ) were prepared by solid state reactions. The phosphors can strongly absorb 393 nm ultraviolet (UV) light which is coupled well emission currently used InGaN-based near UV emitting diodes (LEDs) and emit red a good color purity. luminescent intensity be remarkably enhanced any CC methods. However, shape position excitation spectra keep unchanged. introduction enhance ∼4 times optimal effect. Red also other three but effects are not as because volume unbalance in approach smallest while net positive was offset. results this work suggest that equilibrium mole number should taken into account when selected.

参考文章(15)
V. D. Khalilev, N. V. Suzdal', Crystallization Capacity of ZnB2O4– NaPO3Glasses Glass and Ceramics. ,vol. 61, pp. 145- 147 ,(2004) , 10.1023/B:GLAC.0000043075.60068.1A
P. X. Yan, J. Z. Liu, J. Wang, Z. G. Wu, Overgrowing single crystalline ZnB2O4 on multiwall carbon nanotubes: Straightening the curly tubes Applied Physics Letters. ,vol. 85, pp. 4747- 4749 ,(2004) , 10.1063/1.1821652
Jun-ho Yum, Soo-Yeon Seo, Seonghoon Lee, Yung-Eun Sung, Y 3Al5 O 12 : Ce0.05 Phosphor Coatings on Gallium Nitride for White Light Emitting Diodes Journal of The Electrochemical Society. ,vol. 150, ,(2003) , 10.1149/1.1535207
Juan LI, Chunxiang ZHANG, Qiang TANG, Jingquan HAO, Yanli ZHANG, Qiang SU, Shubin WANG, Photoluminescence and thermoluminescence properties of dysprosium doped zinc metaborate phosphors Journal of Rare Earths. ,vol. 26, pp. 203- 206 ,(2008) , 10.1016/S1002-0721(08)60065-4
Wei-Ren Liu, Chun Che Lin, Yi-Chen Chiu, Yao-Tsung Yeh, Shyue-Ming Jang, Ru-Shi Liu, ZnB2O4:Bi3+,Eu3+:a highly efficient, red-emitting phosphor. Optics Express. ,vol. 18, pp. 2946- 2951 ,(2010) , 10.1364/OE.18.002946
Jeong-Ryeol Kim, Dong-Wan Kim, In-Sun Cho, Byoung Soo Kim, Jae-sul An, Kug Sun Hong, Low temperature sintering and microwave dielectric properties of Ba3Ti5Nb6O28 with ZnO–B2O3 glass additions for LTCC applications Journal of The European Ceramic Society. ,vol. 27, pp. 3075- 3079 ,(2007) , 10.1016/J.JEURCERAMSOC.2006.11.036
Jong Su Kim, Pyung Eun Jeon, Yun Hyung Park, Jun Chul Choi, Hong Lee Park, Gwang Chul Kim, Tae Whan Kim, White-light generation through ultraviolet-emitting diode and white-emitting phosphor Applied Physics Letters. ,vol. 85, pp. 3696- 3698 ,(2004) , 10.1063/1.1808501
Yunhui Zheng, Yuning Qu, Yumei Tian, Chunguang Rong, Zichen Wang, Shengli Li, Xue Chen, Yuejia Ma, Effect of Eu3+-doped on the luminescence properties of zinc borate nanoparticles Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 349, pp. 19- 22 ,(2009) , 10.1016/J.COLSURFA.2009.07.039
Joung Kyu Park, Chang Hae Kim, Seung Hyok Park, Hee Dong Park, Se Young Choi, Application of strontium silicate yellow phosphor for white light-emitting diodes Applied Physics Letters. ,vol. 84, pp. 1647- 1649 ,(2004) , 10.1063/1.1667620
Mao Wu, Xin-bo He, Zhuo-shen Shen, Xuan-hui Qu, Preparation, crystallization, and wetting of ZnO-Al2O3-B2O3-SiO2 glass-ceramics for sealing to Kovar International Journal of Minerals Metallurgy and Materials. ,vol. 16, pp. 586- 591 ,(2009) , 10.1016/S1674-4799(09)60101-1