Partial molar volume of NaCl and CsCl in mixtures of water and methanol by experiment and molecular simulation

摘要: Abstract Densities of solutions NaCl and CsCl in mixtures water methanol are determined by experiment molecular dynamics simulation. Both experiments simulations cover the concentration range up to solubility limit salt temperature 288.15 ≤ T /K 318.15 at ambient pressure. Non-polarizable models from literature used for ions solvents. The partial molar volume salts at infinite dilution mixed solvent is an empirical correlation data. effects on density volumes well predicted models.