Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, β-(NH4)3InF6 and [NH4]3[C6H21N4]2[In4F21]
作者： Adrian A. Finch , Philip Lightfoot , Anil C.A. Jayasundera , Richard J. Goff , Yang Li
DOI: 10.1016/J.JSSC.2009.11.022
关键词:
摘要: Abstract The solvothermal syntheses and crystal structures of three indium fluorides are presented. K5In3F14 (1) β-(NH4)3InF6 (2) variants on known inorganic structure types chiolite cryolite, respectively, with the latter exhibiting a complex apparently novel structural distortion. [NH4]3[C6H21N4]2[In4F21] (3) represents new hybrid composition displaying unique trimeric metal fluoride building unit.
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