Preparation and crystal structure of dimethyltris(trimethylsilyl)methylsilanatolithium tetrahydrofuranate

作者: Peter B. Hitchcock , Nabeel H. Buttrus , Alice C. Sullivan

DOI: 10.1016/0022-328X(86)82033-2

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摘要: Abstract A single crystal X-ray diffraction study has shown that the solid isolated after treatment of (Me 3 Si) CSiMe 2 OH with MeLi in THF is dimeric species [(Me OLi · thf] . Cryoscopy shows product to be a tetramer benzene.

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