Time‐resolved Fourier transform infrared/attenuated total reflection spectroscopy for the measurement of molecular diffusion in polymers

作者: Yossef A. Elabd , Marco Giacinti Baschetti , Timothy A. Barbari

DOI: 10.1002/POLB.10661

关键词:

摘要: Over the past 2 decades, use of time-resolved Fourier transform infrared/attenuated total reflection (ATR) spectroscopy for measurement diffusion in polymers has grown. ATR is a powerful technique because it an situ that relatively inexpensive, provides reliable short-time data, and wealth information at molecular level. This article highlights its application to numerous studies, ranging from drugs human skin chemical warfare agents barrier materials. In addition these topics, recent studies with quantify model interactions during process are reviewed. future, may have impact on variety emerging fields which plays important role, such as fuel cells, membrane separation, sensors, drug delivery.

参考文章(85)
G. Rajagopalan, C. Narayanan, J.W. Gillespie, S.H. McKnight, Diffusion and reaction of epoxy and amine in polysulfone-transport modeling and experimental validation Polymer. ,vol. 41, pp. 8543- 8556 ,(2000) , 10.1016/S0032-3861(00)00251-2
C Mura, J Yarwood, R Swart, D Hodge, Infrared-ATR studies of the hydration and dehydration of formulated PVC films Polymer. ,vol. 42, pp. 4141- 4152 ,(2001) , 10.1016/S0032-3861(00)00688-1
Junghee Han, Young Il Yeom, Specific gene transfer mediated by galactosylated poly-L-lysine into hepatoma cells. International Journal of Pharmaceutics. ,vol. 202, pp. 151- 160 ,(2000) , 10.1016/S0378-5173(00)00441-5
Christopher Sammon, Carine Mura, Jack Yarwood, Neil Everall, Ron Swart, David Hodge, FTIR−ATR Studies of the Structure and Dynamics of Water Molecules in Polymeric Matrixes. A Comparison of PET and PVC Journal of Physical Chemistry B. ,vol. 102, pp. 3402- 3411 ,(1998) , 10.1021/JP980169N
Bui Duc Hanh, Reinhard H.H. Neubert, Siegfried Wartewig, Investigation of drug release from suspension using FTIR-ATR technique: part II. Determination of dissolution coefficient of drugs. International Journal of Pharmaceutics. ,vol. 204, pp. 151- 158 ,(2000) , 10.1016/S0378-5173(00)00487-7
Tracy L. Marshbanks, Elias I. Franses, Transport and Ion-Exchange Dynamics in Langmuir-Blodgett Films of Fatty Acids The Journal of Physical Chemistry. ,vol. 98, pp. 2166- 2173 ,(1994) , 10.1021/J100059A033
Peter Sutandar, Dong June Ahn, Elias I. Franses, FTIR ATR analysis for microstructure and water uptake in poly(methyl methacrylate) spin cast and Langmuir-Blodgett thin films Macromolecules. ,vol. 27, pp. 7316- 7328 ,(1994) , 10.1021/MA00103A013
Yossef A. Elabd, Timothy A. Barbari, Separating solvation from molecular diffusion in polymers Aiche Journal. ,vol. 47, pp. 1255- 1262 ,(2001) , 10.1002/AIC.690470603