Reactivity of the [ReO]3+ core toward Ph2P(Se)NH(Se)PPh2
作者： Roberto Rossi , Andrea Marchi , Lorenza Marvelli , Maurizio Peruzzini , Umberto Casellato
DOI: 10.1039/DT9920000435
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摘要: The salt K[N(PPh2Se)2] reacts with [ReOCl3(PPh3)2] or [AsPh4][ReOCl4] to give [ReO(Cl){N(PPh2Se)2}2]. In solution this compound tends transform into [ReO(Cl)(Ph2PNPPh2Se)2], by loss of one Se atom from each ligand. Recrystallization CH2Cl2–EtOH yielded [ReO(OEt)(Ph2PNPPh2Se)2] the crystal structure which has been determined.
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