Evolution of tribofilms under lubrication conditions experienced in engine valve trains

作者: J.H. Green , A. Morina , M. Priest , A. Neville

DOI: 10.1016/S0167-8922(03)80038-X

关键词:

摘要: A block on ring tribometer employing AISI E52100 steel components, was used to simulate cam and tappet tribology in order evaluate the tribological performance evolution (frictional performance, wear coefficients, surface chemistry species/quantification film structure) tribofilms. Lubricants consisted of a mineral base oil containing zinc dialkyl dithiophosphate (ZDDP) plus full dispersant-detergent-antioxidant package an identical blend but with addition molybdenum dithiocarbamate (MoDTC). Energy Dispersive X-Ray analysis (EDX) X-ray Photoelectron Spectroscopy (XPS) chemical techniques have been employed, allowing crucial link between testing duration properties be evaluated. Factors such as topography due formation hence protection friction control offered, are analysed using Atomic Force Microscopy (AFM). The contrasting frictional difference two lubricants is correlated wear, roughness effects, structure chemistry. relationships running-in service valve train system tribo-chemical parameters this based work discussed. It found that reduction observed primarily consequence tribofilm shear strength changes not nano-scale topography, which comparable magnitude at different coefficients.

参考文章(18)
Jean‐Michel Martin, Carol Grossiord, Karine Varlot, Béatrice Vacher, Jinichi Igarashi, None, Synergistic effects in binary systems of lubricant additives: a chemical hardness approach Tribology Letters. ,vol. 8, pp. 193- 201 ,(2000) , 10.1023/A:1019147520893
P.A. Willermet, Some engine oil additives and their effects on antiwear film formation Tribology Letters. ,vol. 5, pp. 41- 47 ,(1998) , 10.1023/A:1019148415074
Jean Michel Martin, Antiwear mechanisms of zinc dithiophosphate: a chemical hardness approach Tribology Letters. ,vol. 6, pp. 1- 8 ,(1999) , 10.1023/A:1019191019134
JH Green, M Priest, A Morina, A Neville, Approaches to sensitising engine valve train friction models to lubricant formulation characteristics Tribology and Interface Engineering Series. ,vol. 41, pp. 35- 45 ,(2003) , 10.1016/S0167-8922(03)80117-7
Roy M. Mortier, Stefan T. Orszulik, Malcolm F. Fox, Chemistry and Technology of Lubricants ,(1992)
C Grossiord, K Varlot, J.-M Martin, Th Le Mogne, C Esnouf, K Inoue, MoS2 single sheet lubrication by molybdenum dithiocarbamate Tribology International. ,vol. 31, pp. 737- 743 ,(1998) , 10.1016/S0301-679X(98)00094-2
Zhanfeng Yin, Masoud Kasrai, Marina Fuller, G.Michael Bancroft, Kim Fyfe, Kim H. Tan, Application of soft X-ray absorption spectroscopy in chemical characterization of antiwear films generated by ZDDP Part I: the effects of physical parameters Wear. ,vol. 202, pp. 172- 191 ,(1997) , 10.1016/S0043-1648(96)07272-9
J.C. Bell, T.A. Colgan, Crirical physical conditions in the lubrication of automotive valve train systems Tribology International. ,vol. 24, pp. 77- 84 ,(1991) , 10.1016/0301-679X(91)90036-9