Deuterium and Tritium

作者: Joseph J. Katz

DOI: 10.1002/0471238961.0405212011012026.A01.PUB2

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摘要: Deuterium (2H or D) the heavier, stable isotope of hydrogen (1H) occurs in nature, and is always present all hydrogen-containing compounds. oxide, known as heavy water, most important deuterium compound. Heavy water differs from ordinary structure liquid phase, nuclear spin, ionic equilibria, various spectroscopic properties. Kinetic effects occur chemical reactions involving bond rupture H D. This effect exchange between sulfide basis for separation process large-scale production. Infrared absorption method choice analysis water. has far-reaching biological effects, it possible to grow living organisms which normally replaced by deuterium. The properties are such that efficient neutron moderator fission reactors. also fusion technology. Tritium (3H T) heaviest hydrogen. Unlike deuterium, T undergoes radioactive decay (B−, ∼ 12 yr half-life). Thus compounds experience radiation damage at elevated tritium levels. Tritium produced cosmic rays higher atmosphere, capture lithium–aluminum alloy can be purified distillation, thermal diffusion, diffusion through palladium-silver-nickel membranes, chromatography on coated molecular sieves. widely used a tracer biology experiments. key element fusion, energy controlled with deuterium. Keywords: deuterium; tritium; isotopes; heavy hydrogen; heavy water; neutron moderator; superconductivity; deuterium fusion; nuclear fusion; tracers; nuclear magnetic resonance

参考文章(92)
WILLIAM SPINDEL, Isotope separation processes ACS Symp. Ser.; (United States). ,vol. 11, ,(1975) , 10.1021/BK-1975-0011.CH005
A. K. Covington, R. A. Robinson, Roger G. Bates, The Ionization Constant of Deuterium Oxide from 5 to 50 The Journal of Physical Chemistry. ,vol. 70, pp. 3820- 3824 ,(1966) , 10.1021/J100884A011
Christopher. Deverell, Kjeld. Schaumburg, Determination of water-heavy water mixtures by fluorine-19 nuclear magnetic resonance Analytical Chemistry. ,vol. 39, pp. 1879- 1880 ,(1967) , 10.1021/AC50157A068
Dorice M. Czajka, Asher J. Finkel, Conrad S. Fischer, Joseph J. Katz, Physiological effects of deuterium on dogs American Journal of Physiology-Legacy Content. ,vol. 201, pp. 357- 362 ,(1961) , 10.1152/AJPLEGACY.1961.201.2.357
Abraham S. Friedman, Lester Haar, High‐Speed Machine Computation of Ideal Gas Thermodynamic Functions. I. Isotopic Water Molecules Journal of Chemical Physics. ,vol. 22, pp. 2051- 2058 ,(1954) , 10.1063/1.1739991
Robert H. Sherman, John R. Bartlit, D. Kirk Veirs, Experimental Results from Hydrogen/Deuterium Distillations at the Tritium Systems Test Assembly Fusion Technology. ,vol. 6, pp. 625- 628 ,(1984) , 10.13182/FST84-A23144
Wendell Johnson, Roy A. Keller, Nmr Spectroscopic Determination of Water In Deuterium Oxide/Water Mixtures Analytical Letters. ,vol. 2, pp. 99- 104 ,(1969) , 10.1080/00032716908051277
G M McCracken, M Bailey, S Croft, D J S Findlay, A Gibson, R P Govier, O N Jarvis, H J Milton, B A Powell, G Sadler, M R Sene, D R Sweetman, P van Belle, H H H Watson, Experimental search for 'cold fusion' in the deuterium-titanium system Journal of Physics D. ,vol. 23, pp. 469- 475 ,(1990) , 10.1088/0022-3727/23/5/001
A. Dyer, J. C. J. Dean, Application of the double ratio technique to emulsion systems for liquid scintillation counting of3H and14C labelled materials Journal of Radioanalytical and Nuclear Chemistry. ,vol. 141, pp. 139- 154 ,(1990) , 10.1007/BF02060192