Selective adsorption of thorium on activated charcoal from electrolytic aqueous solution

作者: Riaz Qadeer , Javed Hanif , M Saleem , M Afzal , None

DOI: 10.1007/BF02047447

关键词:

摘要: The adsorption of thorium on activated charcoal has been studied as a function shaking time, amount adsorbent, pH, concentration adsorbate and temperature. Adsorption obeys the Langmuir isotherm. ΔH0 ΔS0 were calculated from slope intercept ln KD vs. 1/T plots. influence different anions cations examined. other metal ions under specified conditions to check its selectivity. Consequently, was removed Cs, Co, Ba, Cr, Sr, Cd, Cu, Mn Zn. More than 98% adsorbed can be recovered with 55 ml 3M HNO3 solution. Wavelength dispersive X-rays fluorescence spectrometer used for measuring concentration.

参考文章(18)
M. Afzal, Javed Hanif, Imtiaz Hanif, Riaz Qadeer, M. Saleem, Determination of zirconium and hafnium in solution by X-ray fluorescence spectrometry Journal of Radioanalytical and Nuclear Chemistry Articles. ,vol. 139, pp. 203- 214 ,(1990) , 10.1007/BF02061804
S. Aksoyoglu, Sorption of U(VI) on granite Journal of Radioanalytical and Nuclear Chemistry. ,vol. 134, pp. 393- 403 ,(1989) , 10.1007/BF02278276
M. A. Rauf, S. M. Hasany, M. T. Hussain, ADSORPTION STUDIES OF MERCURY ON ZIRCONIUM OXIDE FROM AQUEOUS SOLUTION Journal of Radioanalytical and Nuclear Chemistry. ,vol. 132, pp. 397- 408 ,(1989) , 10.1007/BF02136099
J. F. King, U. T. Greene, III. The Effect of the Alkali and the Alkaline Earth Ions on the Adsorption of Thorium B by Silver Bromide Crystals. The Journal of Physical Chemistry. ,vol. 37, pp. 1047- 1059 ,(1932) , 10.1021/J150350A009
Charles J. Gallagher, Adsorption of Thorium on Tantalum Physical Review. ,vol. 65, pp. 46- 50 ,(1944) , 10.1103/PHYSREV.65.46
J. F. King, Alfred Romer, I. The Adsorption of Thorium B and Thorium C from,Solution. The Journal of Physical Chemistry. ,vol. 37, pp. 663- 673 ,(1932) , 10.1021/J150348A001
H. W. Kohlsch�tter, W. Katzenmayer, Trennungen des kolloiden Thoriumoxids von Chlorionen in Silicagelsäulen mit verschiedenartigen Funktionen des Silicagels Zeitschrift für anorganische und allgemeine Chemie. ,vol. 329, pp. 163- 171 ,(1964) , 10.1002/ZAAC.19643290119
P.J. Estrup, J. Anderson, W.E. Danforth, LEED studies of thorium adsorption on tungsten Surface Science. ,vol. 4, pp. 286- 298 ,(1966) , 10.1016/0039-6028(66)90007-0
W. H. SEEGERS, M. NIEFT, E. C. LOOMIS, NOTE ON THE ADSORPTION OF THROMBIN ON FIBRIN. Science. ,vol. 101, pp. 520- 521 ,(1945) , 10.1126/SCIENCE.101.2629.520