Microwave spectrum of CH3OD

作者: V.K. Kaushik , K. Takagi , C. Matsumura

DOI: 10.1016/0022-2852(80)90125-3

关键词:

摘要: Abstract The microwave spectrum of CH 3 OD has been observed in the frequency region between 14 and 92 GHz. All ground-state transitions with J ≤ 8 = 2 ← 1, a -type excited torsional states ( v 1 2) have observed. analyzed rotational constants, torsion-vibration-rotation interaction centrifugal distortion constants evaluated. Stark effect measurements made dipole moment components determined as μ 0.833 ± 0.008 D b 1.488 0.015 .

参考文章(24)
Børge Bak, Lise Hansen, John Rastrup‐Andersen, Experimental Evidence of Restricted Rotation in CH3–C≡C–CF3 The Journal of Chemical Physics. ,vol. 21, pp. 1612- 1613 ,(1953) , 10.1063/1.1699313
CHUN C. LIN, JEROME D. SWALEN, Internal Rotation and Microwave Spectroscopy Reviews of Modern Physics. ,vol. 31, pp. 841- 891 ,(1959) , 10.1103/REVMODPHYS.31.841
John Sheridan, Walter Gordy, The Microwave Spectra and Molecular Structures of Trifluorosilane Derivatives The Journal of Chemical Physics. ,vol. 19, pp. 965- 970 ,(1951) , 10.1063/1.1748418
R. M. Lees, F. J. Lovas, W. H. Kirchhoff, D. R. Johnson, Microwave Spectra of Molecules of Astrophysical Interest: III. Methanol Journal of Physical and Chemical Reference Data. ,vol. 2, pp. 205- 214 ,(1973) , 10.1063/1.3253116
John S. Muenter, Electric Dipole Moment of Carbonyl Sulfide Journal of Chemical Physics. ,vol. 48, pp. 4544- 4547 ,(1968) , 10.1063/1.1668024
Eugene V. Ivash, David M. Dennison, The Methyl Alcohol Molecule and Its Microwave Spectrum The Journal of Chemical Physics. ,vol. 21, pp. 1804- 1816 ,(1953) , 10.1063/1.1698668
Bernard Kirtman, Interactions between Ordinary Vibrations and Hindered Internal Rotation. I. Rotational Energies The Journal of Chemical Physics. ,vol. 37, pp. 2516- 2539 ,(1962) , 10.1063/1.1733049
Takashi Itoh, Molecular Structure of Methylamine Journal of the Physical Society of Japan. ,vol. 11, pp. 264- 271 ,(1956) , 10.1143/JPSJ.11.264