Microwave synthesis of magnetoresistive La0.7Ba0.3MnO3 using inorganic precursors

作者: Ranjan Kumar Sahu , Manju Lata Rao , S. Sundar Manoharan

DOI: 10.1023/A:1017931930656

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摘要: We report here the use of inorganic precursors as good microwave absorbers, by virtue its polarity and high dielectric constant, to synthesize temperature stable rare earth manganite, La0.7Ba0.3MnO3. Compared other wet chemical methods, oxides prepared assisted route give fine particle (<30 nm) with effective BET surface area ∼25 m2/g. Two factors contribute rapid synthesis these phases. Firstly, constant employed increases power loss in material this leads a local heating effect. Secondly decomposition precursors, lead formation finely divided often accompanied an exothermic reaction which provides needed energy effect product. This method offers new approach employ starting materials realize fast synthesis.

参考文章(11)
W. H. Sutton, Microwave Processing of Ceramic Materials American Ceramic Society Bulletin. ,vol. 68, pp. 376- 386 ,(1989)
Rustum Roy, Dinesh Agrawal, Jiping Cheng, Shalva Gedevanishvili, Full sintering of powdered-metal bodies in a microwave field Nature. ,vol. 399, pp. 668- 670 ,(1999) , 10.1038/21390
Philippe R. Bonneau, Robert F. Jarvis, Richard B. Kaner, Rapid solid-state synthesis of materials from molybdenum disulphide to refractories Nature. ,vol. 349, pp. 510- 512 ,(1991) , 10.1038/349510A0
M. Verelst, N. Rangavittal, C.N.R. Rao, A. Rousset, Metal-Insulator Transitions in Anion-Excess LaMnO3+δ Controlled by the Mn4+ Content Journal of Solid State Chemistry. ,vol. 104, pp. 74- 80 ,(1993) , 10.1006/JSSC.1993.1142
David R. Baghurst, D. Michael P. Mingos, Application of microwave heating techniques for the synthesis of solid state inorganic compounds Journal of The Chemical Society, Chemical Communications. pp. 829- 830 ,(1988) , 10.1039/C39880000829
H. L. Ju, J. Gopalakrishnan, J. L. Peng, Qi Li, G. C. Xiong, T. Venkatesan, R. L. Greene, Dependence of giant magnetoresistance on oxygen stoichiometry and magnetization in polycrystalline La0.67Ba0.33MnOz Physical Review B. ,vol. 51, pp. 6143- 6146 ,(1995) , 10.1103/PHYSREVB.51.6143
K J Rao, P D Ramesh, Use of microwaves for the synthesis and processing of materials Bulletin of Materials Science. ,vol. 18, pp. 447- 465 ,(1995) , 10.1007/BF02749773
A. Gavin Whittaker, D. Michael P. Mingos, Microwave-assisted solid-state reactions involving metal powders Journal of the Chemical Society, Dalton Transactions. pp. 2073- 2079 ,(1995) , 10.1039/DT9950002073
S. Sundar Manoharan, Kashinath C. Patil, Combustion Synthesis of Metal Chromite Powders Journal of the American Ceramic Society. ,vol. 75, pp. 1012- 1015 ,(1992) , 10.1111/J.1151-2916.1992.TB04177.X