作者: D. Cory , A. Wong , W.M. Ritchey
DOI: 10.1016/S0022-328X(00)96081-9
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摘要: Abstract 29 Si NMR chemical shifts of simple alkylhalosilanes have been shown to follow an additive relation with first and second order coefficients. Grant Paul's method is extended 175 pieces data are fit 32 dependent variables a correlation 0.994 standard error 7.67 ppm. The relative importance the diamagnetic term in shielding expression discussed.