I. Additive relations in alkylhalosilanes

作者: D. Cory , A. Wong , W.M. Ritchey

DOI: 10.1016/S0022-328X(00)96081-9

关键词:

摘要: Abstract 29 Si NMR chemical shifts of simple alkylhalosilanes have been shown to follow an additive relation with first and second order coefficients. Grant Paul's method is extended 175 pieces data are fit 32 dependent variables a correlation 0.994 standard error 7.67 ppm. The relative importance the diamagnetic term in shielding expression discussed.

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