Recent progress in the development of Li2MnSiO4 cathode materials

作者: R.J. Gummow , Y. He

DOI: 10.1016/J.JPOWSOUR.2013.11.082

关键词:

摘要: Lithium ion batteries are under intense development to meet the performance specifications for consumer applications in portable electronic devices, electric vehicle and stationary storage as back-up intermittent renewable energy generation technologies. The most expensive capacity-limiting component these battery systems is cathode material. Research has been directed of novel materials with high capacity density lithium transition metal orthosilicates have identified possible cathodes. In this review we focus on recent developments study Li2MnSiO4 its derivatives a lithium-ion Preparation techniques, structural issues, conductivity enhancement complex morphologies discussed, show improvements limitations synthesis electrochemical performance.

参考文章(54)
Naoaki Yabuuchi, Tsutomu Ohzuku, Electrochemical behaviors of LiCo1/3Ni1/3Mn1/3O2 in lithium batteries at elevated temperatures Journal of Power Sources. ,vol. 146, pp. 636- 639 ,(2005) , 10.1016/J.JPOWSOUR.2005.03.080
A. K. Padhi, K. S. Nanjundaswamy, C. Masquelier, S. Okada, J. B. Goodenough, Effect of Structure on the Fe3 + / Fe2 + Redox Couple in Iron Phosphates Journal of The Electrochemical Society. ,vol. 144, pp. 1609- 1613 ,(1997) , 10.1149/1.1837649
Tsutomu Ohzuku, Atsushi Ueda, Norihiro Yamamoto, Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells Journal of The Electrochemical Society. ,vol. 142, pp. 1431- 1435 ,(1995) , 10.1149/1.2048592
T. Muraliganth, K. R. Stroukoff, A. Manthiram, Microwave-Solvothermal Synthesis of Nanostructured Li2MSiO4/C (M = Mn and Fe) Cathodes for Lithium-Ion Batteries Chemistry of Materials. ,vol. 22, pp. 5754- 5761 ,(2010) , 10.1021/CM102058N
Anton Nytén, Saeed Kamali, Lennart Häggström, Torbjörn Gustafsson, John O. Thomas, The lithium extraction/insertion mechanism in Li2FeSiO4 Journal of Materials Chemistry. ,vol. 16, pp. 2266- 2272 ,(2006) , 10.1039/B601184E
N. Ravet, Y. Chouinard, J.F. Magnan, S. Besner, M. Gauthier, M. Armand, Electroactivity of natural and synthetic triphylite Journal of Power Sources. ,vol. 97, pp. 503- 507 ,(2001) , 10.1016/S0378-7753(01)00727-3
Hugues Duncan, Abhinay Kondamreddy, Patrick H.J. Mercier, Yvon Le Page, Yaser Abu-Lebdeh, Martin Couillard, Pamela S. Whitfield, Isobel J. Davidson, Novel Pn Polymorph for Li2MnSiO4 and Its Electrochemical Activity As a Cathode Material in Li-Ion Batteries Chemistry of Materials. ,vol. 23, pp. 5446- 5456 ,(2011) , 10.1021/CM202793J
V.V. Politaev, A.A. Petrenko, V.B. Nalbandyan, B.S. Medvedev, E.S. Shvetsova, Crystal structure, phase relations and electrochemical properties of monoclinic Li2MnSiO4 Journal of Solid State Chemistry. ,vol. 180, pp. 1045- 1050 ,(2007) , 10.1016/J.JSSC.2007.01.001