Vibrational spectroscopic study of the uranyl selenite mineral derriksite Cu4UO2(SeO3)2(OH)6⋅H2O
作者： Jiří Čejka , Ricardo Scholz , Andrés López , Frederick L. Theiss , Yunfei Xi
DOI: 10.1016/J.SAA.2013.08.026
关键词:
摘要: Raman spectrum of the mineral derriksite Cu4UO2(SeO3)2(OH)6⋅H2O was studied and complemented by infrared this mineral. Both spectra were interpreted partly compared with demesmaekerite, marthozite, larisaite, haynesite piretite. Observed bands attributed to (UO2)2+, (SeO3)2−, (OH)− H2O vibrations. The presence symmetrically distinct hydrogen bonded molecule water crystallization hydroxyl ions inferred from in unit cell. Approximate U–O bond lengths uranyl O–H⋯O calculated derriksite.
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sci-hub.se 参考文章(27)
John W. Anthony, Handbook of mineralogy Mineral Data Pub.. ,(1990)
Ray L. Frost, Matt L. Weier, Thor Bostrom, Jiří Čejka, Wayde Martens, Molecular structure of the uranyl mineral zippeite – An XRD, SEM and Raman spectroscopic study Neues Jahrbuch Fur Mineralogie-abhandlungen. ,vol. 181, pp. 271- 280 ,(2005) , 10.1127/0077-7757/2005/0022
Jiří Čejka, Jiří Sejkora, Ray L. Frost, Eloise C. Keeffe, Raman spectroscopic study of the uranyl mineral natrouranospinite (Na2,Ca)[(UO2)(AsO4)]2· 5H2O Journal of Raman Spectroscopy. ,vol. 40, pp. 1521- 1526 ,(2009) , 10.1002/JRS.2233
D. Ginderow, F. Cesbron, Structure de la derriksite, Cu4(UO2)(SeO3)2(OH)6 Acta Crystallographica Section C-crystal Structure Communications. ,vol. 39, pp. 1605- 1607 ,(1983) , 10.1107/S0108270183009439
D. Ginderow, F. Cesbron, Structure de la demesmaekerite, Pb2Cu5(SeO3)6(UO2)2(OH)6.2H2O Acta Crystallographica Section C Crystal Structure Communications. ,vol. 39, pp. 824- 827 ,(1983) , 10.1107/S0108270183006496
Nikita V. Chukanov, Dmitry Y.u. Pushcharovsky, Marco Pasero, Stefano Merlino, Anna V. Barinova, Steffen Mö ckel, Igor V. Pekov, Aleksandr E. Zadov, Viktor T. Dubinchuk, Larisaite, Na(H3O)(UO2)3(SeO3)2O2 . 4H2O, a new uranyl selenite mineral from Repete mine, San Juan County, Utah, U.S.A. European Journal of Mineralogy. ,vol. 16, pp. 367- 374 ,(2004) , 10.1127/0935-1221/2004/0016-0367
Ray L. Frost, Kristy L. Erickson, Matt L. Weier, Onuma Carmody, Jiří Čejka, Raman spectroscopic study of the uranyl tricarbonate mineral liebigite Journal of Molecular Structure. ,vol. 737, pp. 173- 181 ,(2005) , 10.1016/J.MOLSTRUC.2004.10.033
Ray L. Frost, B. Jagannadha Reddy, Marilla J. Dickfos, An application of near infrared and mid-infrared spectroscopy to the study of uranyl selenite minerals: derriksite, demesmaekerite, guilleminite and haynesite Journal of Near Infrared Spectroscopy. ,vol. 16, pp. 455- 469 ,(2008) , 10.1255/JNIRS.813
P. C. Burns, U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES Canadian Mineralogist. ,vol. 43, pp. 1839- 1894 ,(2005) , 10.2113/GSCANMIN.43.6.1839
D.Yu. Pushcharovsky, R.K. Rastsvetaeva, H. Sarp, Crystal structure of deloryite, Cu4(UO2)[Mo2O8](OH)6 Journal of Alloys and Compounds. ,vol. 239, pp. 23- 26 ,(1996) , 10.1016/0925-8388(96)02271-2