Kinetics of Mercury(II) Transport Through a Bulk Liquid Membrane Containing Calix[4]arene Derivatives as Carrier
作者： H. Korkmaz Alpoguz , Shahabuddin Memon , Mustafa Ersoz , Mustafa Yilmaz
DOI: 10.1081/SS-120019098
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摘要: The kinetics of transport mercury (II) ions through a bulk liquid membrane (chloroform) containing calix[4]arene nitrile derivatives as carrier was examined at different temperatures and stirring rates. could be analyzed in the formalism two, consecutive, irreversible first-order reactions. influence temperature rate on kinetic parameters also have been investigated. entrance rate, k1, exit k2, increased with increasing rate. For maximum fluxes, activation energies were found 1.923 ± 0.15 2.112 0.2 kj/mol, for ligand 1 2, respectively. values energy indicate that process is controlled by species diffusion.
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