Solvation energy of ions in dipolar solvents
作者： Frank Garisto , P. G. Kusalik , G. N. Patey
DOI: 10.1063/1.445735
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摘要: The solvation energy of hard spherical ions immersed in dipolar sphere solvents is investigated as a function ion diameter. We apply both the mean and linearized hypernetted‐chain approximations show that for physically realistic size theories give qualitatively similar results. obtained sum two competing terms: UID, direct ion–solvent interaction energy, which negative, UDD, change solvent–solvent per at infinite dilution. UDD found to be positive make an important contribution all diameters.
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