Enantioselectivity of Nickel Catalysts Modified with Tartaric Acid or Nickel Tartrate Complexes

作者: A HOEK

DOI: 10.1016/0021-9517(79)90265-3

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摘要: On the basis of our model proposed previously physical and chemical variables affecting modification Ni catalysts with tartaric acid or nickel tartrate were varied systematically. The results permitted an optimization catalyst leading to high enantioselectivity. Kinetic parameters determined for gas-phase hydrogenation.

参考文章(15)
J GROENEWEGEN, The infrared spectrum of glycine chemisorbed by supported nickel Journal of Catalysis. ,vol. 27, pp. 369- 373 ,(1972) , 10.1016/0021-9517(72)90172-8
J GROENEWEGEN, Mechanism of asymmetric hydrogenation on modified nickel catalysts Journal of Catalysis. ,vol. 38, pp. 501- 504 ,(1975) , 10.1016/0021-9517(75)90117-7
Olaf Hougen, Engineering Aspects of Solid Catalysts Industrial & Engineering Chemistry. ,vol. 53, pp. 509- 528 ,(1961) , 10.1021/IE50619A020
C. K. Prout, J. R. Carruthers, F. J. C. Rossotti, Structure and stability of carboxylate complexes. Part VII. Crystal and molecular structures of copper(II)meso-tartrate trihydrate and copper(II)d-tartrate trihydrate Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 3336- 3342 ,(1971) , 10.1039/J19710003336
Susumu Tatsumi, Asymmetric Hydrogenating Activity of Modified Raney Nickel Catalyst Bulletin of the Chemical Society of Japan. ,vol. 41, pp. 408- 418 ,(1968) , 10.1246/BCSJ.41.408
R.E. Tapscott, Isomer stabilities of tartrate-bridged binuclear complexes Inorganica Chimica Acta. ,vol. 10, pp. 183- 189 ,(1974) , 10.1016/S0020-1693(00)86730-4
Allan Zalkin, David H. Templeton, Tatzuo Ueki, Crystal structure of l-tris(1,10-phenathroline)iron(II) bis(antimony(III) d-tartrate) octahydrate Inorganic Chemistry. ,vol. 12, pp. 1641- 1646 ,(1973) , 10.1021/IC50125A033
J. H. Ritsma, G. A. Wiegers, F. Jellinek, Stability constants of nickel (II), cobalt (II) and copper (II) complexes of some optically active and racemic amino-acids Recueil des Travaux Chimiques des Pays-Bas. ,vol. 84, pp. 1577- 1584 ,(2010) , 10.1002/RECL.19650841207