Fabrication of OPVs by introducing a conductivity-enhanced hybrid buffer layer
作者： Soo Won Heo , In Sung Song , Young Sung Kim , Doo Kyung Moon
DOI: 10.1016/J.SOLMAT.2012.01.027
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摘要: Abstract Organic photovoltaic cells (OPVs) with a conductivity enhanced by doping either dimethylsulfoxide (DMSO) or ethylene glycol (EG) were successfully fabricated to increase the photon harvesting property through localized surface plasmon resonance (LSPR) adding Au nanoparticles PH500, hole collection layer, and effectively separating generated charges. At nanoparticle DMSO concentrations of 20 wt% 1 wt%, respectively, characteristics OPVs optimized short-circuit current density (Jsc), open-circuit voltage (Voc), fill factor (FF) estimated power conversion efficiency (PCE) 8.0 mA/cm2, 0.595 V, 57.8% 2.6%, respectively. Compared device buffer layer conventional PEDOT:PSS, PCE was improved ca. 85%. The series resistance (Rs), shunt (Rsh), mobility 18 Ω cm2, 673 Ω cm2 4.2 cm2/Vs,
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sci-hub.se 参考文章(30)
Chia-Chien Chang, Hsin-Lun Wu, Chun-Hong Kuo, Michael H. Huang, Hydrothermal Synthesis of Monodispersed Octahedral Gold Nanocrystals with Five Different Size Ranges and Their Self-Assembled Structures Chemistry of Materials. ,vol. 20, pp. 7570- 7574 ,(2008) , 10.1021/CM8021984
J.Y. Kim, J.H. Jung, D.E. Lee, J. Joo, Enhancement of electrical conductivity of poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) by a change of solvents Synthetic Metals. ,vol. 126, pp. 311- 316 ,(2002) , 10.1016/S0379-6779(01)00576-8
Eva Bundgaard, Ole Hagemann, Matthieu Manceau, Mikkel Jørgensen, Frederik C. Krebs, Low Band Gap Polymers for Roll-to-Roll Coated Polymer Solar Cells Macromolecules. ,vol. 43, pp. 8115- 8120 ,(2010) , 10.1021/MA1015903
E. Hutter, J. H. Fendler, Exploitation of Localized Surface Plasmon Resonance Advanced Materials. ,vol. 16, pp. 1685- 1706 ,(2004) , 10.1002/ADMA.200400271
Soon Ok Jeon, Jun Yeob Lee, Improved high temperature stability of organic solar cells using a phosphine oxide type cathode modification layer Solar Energy Materials and Solar Cells. ,vol. 95, pp. 1102- 1106 ,(2011) , 10.1016/J.SOLMAT.2010.12.022
Jonas Weickert, Ricky B. Dunbar, Holger C. Hesse, Wolfgang Wiedemann, Lukas Schmidt-Mende, Nanostructured Organic and Hybrid Solar Cells Advanced Materials. ,vol. 23, pp. 1810- 1828 ,(2011) , 10.1002/ADMA.201003991
Jang-Yong Lee, Min-Hee Choi, Ho-Jun Song, Doo-Kyung Moon, Random copolymers based on 3-hexylthiophene and benzothiadiazole with induced π-conjugation length and enhanced open-circuit voltage property for organic photovoltaics Journal of Polymer Science Part A. ,vol. 48, pp. 4875- 4883 ,(2010) , 10.1002/POLA.24280
Vishal Shrotriya, Elbert Hsing-En Wu, Gang Li, Yan Yao, Yang Yang, Efficient light harvesting in multiple-device stacked structure for polymer solar cells Applied Physics Letters. ,vol. 88, pp. 064104- ,(2006) , 10.1063/1.2172741
Yuan Zhang, Paul W. M. Blom, Electron and hole transport in poly(fluorene-benzothiadiazole) Applied Physics Letters. ,vol. 98, pp. 143504- ,(2011) , 10.1063/1.3574907
Jan Alstrup, Mikkel Jørgensen, Andrew J. Medford, Frederik C. Krebs, Ultra fast and parsimonious materials screening for polymer solar cells using differentially pumped slot-die coating. ACS Applied Materials & Interfaces. ,vol. 2, pp. 2819- 2827 ,(2010) , 10.1021/AM100505E