Two coordination polymers constructed by 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic acid and 2,2'-bipyridine: syntheses, structures and luminescence properties.
作者： Yuan-Chun He , Li-Yuan Xiao , Zi-Han Yuan , Jie Zhang , Yan Wang
DOI: 10.1107/S2053229619014633
关键词:
摘要: Coordination polymers (CPs) have attracted increasing interest in recent years. In this work, two new CPs, namely poly[[aquabis(2,2′-bipyridine-κ2N,N′){μ3-5-[(4-carboxylatophenoxy)methyl]benzene-1,3-dicarboxylato-κ4O1,O1′:O3:O5}(μ-formato-κ3O:O,O′)dicadmium(II)] monohydrate], {[Cd2(C16H9O7)(HCO2)(C10H8N2)2(H2O)]·H2O}n (1), and poly[[(2,2′-bipyridine-κ2N,N′){μ3-5-[(4-carboxylphenoxy)methyl]benzene-1,3-dicarboxylato-κ4O1,O1′:O3:O5}manganese(II)] sesquihydrate], {[Mn(C16H10O7)(C10H8N2)]·1.5H2O}n (2), been prepared using the tricarboxylic acid 5-[(4-carboxyphenoxy)methyl]benzene-1,3-dicarboxylic 2,2′-bipyridine under hydrothermal conditions. CP 1 displays a two-dimensional layer structure which is further extended into three-dimensional (3D) supramolecular via intermolecular π–π interactions, while 2 shows different 3D from one-dimensional ladder chains by interactions. addition, solid-state luminescence spectra of were studied at room temperature.
sci-hub.st 参考文章(29)
Jie Ma, Fei-Long Jiang, Kang Zhou, Lian Chen, Ming-Yan Wu, Mao-Chun Hong, Effects of Temperature and Anion on the Copper(II) Complexes based on 2‐(Carboxyphenyl)iminodiacetic Acid and 1,10‐Phenanthroline Zeitschrift für anorganische und allgemeine Chemie. ,vol. 641, pp. 1998- 2004 ,(2015) , 10.1002/ZAAC.201500164
George M. Sheldrick, Crystal structure refinement with SHELXL Acta Crystallographica Section C-crystal Structure Communications. ,vol. 71, pp. 3- 8 ,(2015) , 10.1107/S2053229614024218
Shu-quan Zhang, Fei-long Jiang, Yang Bu, Ming-yan Wu, Jie Ma, Xiao-chen Shan, Ke-cai Xiong, Mao-chun Hong, Two dual-emissive Zn(II) coordination polymers with tunable photoluminescence properties CrystEngComm. ,vol. 14, pp. 6394- 6396 ,(2012) , 10.1039/C2CE25880C
Fan-Jin Meng, Heng-Qing Jia, Ning-Hai Hu, Jing-Wei Xu, pH-controlled synthesis of two new coordination polymers modeled by pyridine-2,4-dicarboxylic acid Inorganic Chemistry Communications. ,vol. 21, pp. 186- 190 ,(2012) , 10.1016/J.INOCHE.2012.04.012
Lai-Ping Zhang, Jian-Fang Ma, Jin Yang, Ying-Ying Liu, Guo-Hua Wei, 1D, 2D, and 3D Metal−Organic Frameworks Based on Bis(imidazole) Ligands and Polycarboxylates: Syntheses, Structures, and Photoluminescent Properties Crystal Growth & Design. ,vol. 9, pp. 4660- 4673 ,(2009) , 10.1021/CG900460K
Bo Liu, Guo-Ping Yang, Yao-Yu Wang, Rui-Ting Liu, Lei Hou, Qi-Zhen Shi, Two new pH-controlled metal–organic frameworks based on polynuclear secondary building units with conformation-flexible cyclohexane-1,2,4,5-tetracarboxylate ligand Inorganica Chimica Acta. ,vol. 367, pp. 127- 134 ,(2011) , 10.1016/J.ICA.2010.12.023
Yuanjing Cui, Yanfeng Yue, Guodong Qian, Banglin Chen, Luminescent Functional Metal–Organic Frameworks Chemical Reviews. ,vol. 112, pp. 1126- 1162 ,(2012) , 10.1021/CR200101D
Lai-Ping Zhang, Jian-Fang Ma, Jin Yang, Yuan-Yuan Pang, Ji-Cheng Ma, Series of 2D and 3D Coordination Polymers Based on 1,2,3,4-Benzenetetracarboxylate and N-Donor Ligands: Synthesis, Topological Structures, and Photoluminescent Properties Inorganic Chemistry. ,vol. 49, pp. 1535- 1550 ,(2010) , 10.1021/IC9019553
Stuart R Batten, Neil R Champness, Xiao-Ming Chen, Javier Garcia-Martinez, Susumu Kitagawa, Lars Öhrström, Michael O’keeffe, Myunghyun Paik Suh, Jan Reedijk, None, Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013) Pure and Applied Chemistry. ,vol. 85, pp. 1715- 1724 ,(2013) , 10.1351/PAC-REC-12-11-20
Yun Wang, Jin Yang, Ying-Ying Liu, Jian-Fang Ma, Controllable Syntheses of Porous Metal–Organic Frameworks: Encapsulation of LnIII Cations for Tunable Luminescence and Small Drug Molecules for Efficient Delivery Chemistry: A European Journal. ,vol. 19, pp. 14591- 14599 ,(2013) , 10.1002/CHEM.201300144