A new surface equation of state: Hydrophobic–hydrophilic contributions to the activity coefficient
作者： Josefina Viades-Trejo , Jesús Gracia-Fadrique
DOI: 10.1016/J.FLUID.2007.10.012
关键词:
摘要: A new surface equation of state with two thermodynamic parameters: the critical micellar concentration and compressibility factor is presented, which comes from experimental evidence equality Volmer's chemical potential bulk at diluted region under symmetric activity coefficients convention. The contains in its boundaries exact relationship between standard Gibbs energy adsorption micellization, additionally allows interpretation coefficient infinite dilution light hydrophobic effect.
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