Hydrogen- and C 1–C 3 Hydrocarbon-Nitrous Oxide Kinetics in Freely Propagating and Burner-Stabilized Flames, Shock Tubes, and Flow Reactors

作者: O. A. Powell , P. Papas , C. B. Dreyer

DOI: 10.1080/00102200903357724

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摘要: A detailed, chemical mechanism has been compiled for modeling the combustion of C 1–C 3 hydrocarbon-nitrous oxide mixtures. The compiled, compared and validated against available data in literature, including flame structure measurements hydrogen-nitrous ammonia-nitrous flames, flow reactor on moist, nitrous decomposition mixtures, shock tube ignition delay hydrogen- methane-nitrous experimental speed carbon monoxide-nitrous experimental, laminar hydrogen-, methane-, acetylene-, propane-nitrous Feature sensitivity studies reaction path analyses have employed to elucidate important pathways overall rate these systems, include step (N 2 O(+M) ⇌ N 2 + O(+M)) reactions with H atoms O + H ⇌ N 2 + OH N O + H ⇌ NH + NO). Modificati...

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