Identification of black pigments on prehistoric Southwest American potsherds by infrared and Raman microscopy

作者: Jaap van der Weerd , Gregory D Smith , Steven Firth , Robin J.H Clark

DOI: 10.1016/J.JAS.2004.03.008

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摘要: Abstract Raman and infrared microscopy have been used to characterise the black pigments on prehistoric Southwest American black-on-white pottery. Conclusive spectroscopic evidence for use of carbon-based paints these sherds has provided using technique. Maghaemite (γ-Fe 2 O 3 ) magnetite (Fe 4 ), found alternatively or mixed with a carbonaceous pigment, were also identified some sherds. Infrared measurements indicated that little, if any, organic material from biogenic precursors pigment binding agents remained in paints. These results obtained rapidly non-destructively unprepared samples, resulting data complement, instances correct, paint type conclusions drawn studies involving techniques such as XRD, SEM-EDX, XPS.

参考文章(30)
E. Ciliberto, G. Spoto, Modern analytical methods in art and archaeology Wiley. ,(2000)
John Winter, The characterization of pigments based on carbon Studies in Conservation. ,vol. 28, pp. 49- 66 ,(1983) , 10.1179/SIC.1983.28.2.49
Olga N. Shebanova, Peter Lazor, Raman study of magnetite (Fe3O4): laser‐induced thermal effects and oxidation Journal of Raman Spectroscopy. ,vol. 34, pp. 845- 852 ,(2003) , 10.1002/JRS.1056
N. Q. Liem, N. T. Thanh, Ph. Colomban, Reliability of Raman micro-spectroscopy in analysing ancient ceramics: the case of ancient Vietnamese porcelain and celadon glazes Journal of Raman Spectroscopy. ,vol. 33, pp. 287- 294 ,(2002) , 10.1002/JRS.854
G. L. Carr, J. A. Reffner, G. P. Williams, Performance of an infrared microspectrometer at the NSLS Review of Scientific Instruments. ,vol. 66, pp. 1490- 1492 ,(1995) , 10.1063/1.1145951
Jian Zuo, Cunyi Xu, Changsui Wang, Zhang Yushi, Identification of the pigment in painted pottery from the Xishan site by Raman microscopy Journal of Raman Spectroscopy. ,vol. 30, pp. 1053- 1055 ,(1999) , 10.1002/(SICI)1097-4555(199912)30:12<1053::AID-JRS473>3.0.CO;2-F
Ian M. Bell, Robin J.H. Clark, Peter J. Gibbs, Raman spectroscopic library of natural and synthetic pigments (pre- ≈ 1850 AD) Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 53, pp. 2159- 2179 ,(1997) , 10.1016/S1386-1425(97)00140-6
D. L. A. de Faria, S. Venâncio Silva, M. T. de Oliveira, Raman microspectroscopy of some iron oxides and oxyhydroxides Journal of Raman Spectroscopy. ,vol. 28, pp. 873- 878 ,(1997) , 10.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO;2-B
Lucia Burgio, Robin J.H Clark, Library of FT-Raman spectra of pigments, minerals, pigment media and varnishes, and supplement to existing library of Raman spectra of pigments with visible excitation. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 57, pp. 1491- 1521 ,(2001) , 10.1016/S1386-1425(00)00495-9