Ionic comonomer effect of poly(N-isopropylacrylamide) copolymer containing D-π-A type pyran-based fluorescent dye.
作者： Eun-Mi Lee , Seon-Young Gwon , In-Jeong Hwang , Young-A Son , Sung-Hoon Kim
DOI: 10.1016/J.SAA.2012.02.035
关键词:
摘要: Temperature and pH responsive poly(N-isopropylacrylamide) (poly(NIPAM)) copolymer containing D-π-A type pyran-based fluorescent dye (fluorophore) basic comonomer, N-[3-(dimethylamino)propyl]-methacrylamide (DMAPAM) was prepared by free radical polymerization. With increase of values, aqueous poly(NIPAM-co-DMAPAM-co-fluorophore) solution showed decrease a lower critical temperature (LCST) fluorescence intensity, due to change in the ionization state. And also hydrodynamic radius changed correspondingly changes values.
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