{1,1'-[(2,2-Dimethyl-propane-1,3-di-yl)bis-(nitrilo-methyl-idyne)]di-2-naphthol-ato}dioxidomolybdenum(VI) dichloro-methane 1.75-solvate.
作者： Niaz Monadi , Iran Sheikhshoaie , Abdoreza Rezaeifard , Helen Stoeckli-Evans
DOI: 10.1107/S1600536809032759
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摘要: In the crystal structure of title compound, [Mo(C27H24N2O2)O2]·1.75CH2Cl2, MoVI ion is coordinated by two oxide O atoms and N tetradentate 1,1′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethylidyne)]di-2-naphtholate Schiff base ligand in a distorted octahedral configuration. The compound crystallizes with 1.75 molecules dichloromethane per complex molecule. crystal, symmetry-related molecules are linked number C—H⋯O interactions involving both partly disordered solvent molecules, leading to formation two-dimensional network extending parallel (101).
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