Study of Curing Kinetics of an Epoxy-Amine Adhesive System Using a Calorimetric Analysis Approach
作者： Xiaoping Guo
DOI: 10.1080/03602550802391391
关键词:
摘要: Various dynamic curing experiments for an epoxy-amine adhesive system were conducted using a differential scanning calorimetry. The obtained data corrected proposed baseline method, and fitted to generalized autocatalytic model of chemical reaction determine the parameters. It was shown that with classical fourth-order Runge-Kutta numerical algorithm, kinetic as derived from could be used reliably simulate industrial process, which may include nonisothermal quasi-isothermal steps. In addition, various performed; heat flows cure measured, numerically compared relevant calculations.
sci-hub.se 参考文章(18)
Kris Neville, Henry Lee, Handbook of Epoxy Resins ,(1967)
Charles G Hill, Introduction to Chemical Engineering Kinetics & Reactor Design ,(1977)
J. H. Flynn, A general differential technique for the determination of parameters for d(α)/dt=f(α)A exp (−E/RT) Journal of Thermal Analysis and Calorimetry. ,vol. 37, pp. 293- 305 ,(1991) , 10.1007/BF02055932
A. A. Skordos, I. K. Partridge, Cure kinetics modeling of epoxy resins using a non‐parametric numerical procedure Polymer Engineering and Science. ,vol. 41, pp. 793- 805 ,(2001) , 10.1002/PEN.10777
H. E. Kissinger, Reaction Kinetics in Differential Thermal Analysis Analytical Chemistry. ,vol. 29, pp. 1702- 1706 ,(1957) , 10.1021/AC60131A045
U. Bandara, A systematic solution to the problem of sample background correction in DSC curves Journal of Thermal Analysis and Calorimetry. ,vol. 31, pp. 1063- 1071 ,(1986) , 10.1007/BF02119261
A. Cherdoud-Chihani, M. Mouzali, M. J. M. Abadie, Study of crosslinking AMS/DGEBA system by FTIR Journal of Applied Polymer Science. ,vol. 69, pp. 1167- 1178 ,(1998) , 10.1002/(SICI)1097-4628(19980808)69:6<1167::AID-APP14>3.0.CO;2-Q
X RAMIS, Effect of the inhibitor on the curing of an unsaturated polyester resin Polymer. ,vol. 36, pp. 3511- 3521 ,(1995) , 10.1016/0032-3861(95)92023-8
T. Ozawa, Kinetic analysis of derivative curves in thermal analysis Journal of Thermal Analysis and Calorimetry. ,vol. 2, pp. 301- 324 ,(1970) , 10.1007/BF01911411
Steven Swier, Bruno Van Mele, Mechanistic Modeling of the Epoxy−Amine Reaction in the Presence of Polymeric Modifiers by Means of Modulated Temperature DSC Macromolecules. ,vol. 36, pp. 4424- 4435 ,(2003) , 10.1021/MA034118M