An Investigation of the Effect of Chitosan on Isothermal Crystallization, Thermal Decomposition, and Melt Index of Biodegradable Poly(L-lactic acid)

作者: Yan-Hua Cai , Li-Sha Zhao

DOI: 10.1155/2015/296380

关键词:

摘要: Biodegradable chitosan (CS) was introduced into another biodegradable poly(L-lactic acid) (PLLA) to prepare the PLLA/CS composites, and effect of CS on thermal behavior melt index PLLA investigated using modern testing technologies including optical depolarizer, thermogravimetric analysis instrument, instrument. The relevant results showed that both crystallization temperature concentration affected isothermal PLLA. Compared neat PLLA, t1/2 PLLA/5% decreased from 2991.54 s minimum value 208.76 s at 105°C. However, composites in high zone different low zone. increase heating rate made decomposition shift higher temperature. indicated 3% fluidity become better.

参考文章(15)
Huili Li, Qing Xu, Yun Chen, Ajun Wan, Effect of concentration and molecular weight of chitosan and its derivative on the free radical scavenging ability Journal of Biomedical Materials Research Part A. ,vol. 102, pp. 911- 916 ,(2014) , 10.1002/JBM.A.34749
Desireddy Harikishore Kumar Reddy, Seung-Mok Lee, Synthesis and characterization of a chitosan ligand for the removal of copper from aqueous media Journal of Applied Polymer Science. ,vol. 130, pp. 4542- 4550 ,(2013) , 10.1002/APP.39578
Vimal Kumar, Anshu Dev, A.P. Gupta, Studies of poly(lactic acid) based calcium carbonate nanocomposites Composites Part B-engineering. ,vol. 56, pp. 184- 188 ,(2014) , 10.1016/J.COMPOSITESB.2013.08.021
Manlin Li, Juan Xu, Ronghua Li, Dongen Wang, Tianbao Li, Maosen Yuan, Jinyi Wang, Simple preparation of aminothiourea-modified chitosan as corrosion inhibitor and heavy metal ion adsorbent. Journal of Colloid and Interface Science. ,vol. 417, pp. 131- 136 ,(2014) , 10.1016/J.JCIS.2013.11.053
Kaimeng Xu, Kaifu Li, Tuhua Zhong, Litao Guan, Chengping Xie, Shan Li, Effects of chitosan as biopolymer coupling agent on the thermal and rheological properties of polyvinyl chloride/wood flour composites Composites Part B-engineering. ,vol. 58, pp. 392- 399 ,(2014) , 10.1016/J.COMPOSITESB.2013.10.056
Mi Yeong Jo, Yeon Jong Ryu, Jun Hee Ko, Jin-San Yoon, Effects of compatibilizers on the mechanical properties of ABS/PLA composites Journal of Applied Polymer Science. ,vol. 125, ,(2012) , 10.1002/APP.36732
S. Vimal, S. Abdul Majeed, G. Taju, K.S.N. Nambi, N. Sundar Raj, N. Madan, M.A. Farook, T. Rajkumar, D. Gopinath, A.S. Sahul Hameed, RETRACTED: Chitosan tripolyphosphate (CS/TPP) nanoparticles: Preparation, characterization and application for gene delivery in shrimp Acta Tropica. ,vol. 128, pp. 486- 493 ,(2013) , 10.1016/J.ACTATROPICA.2013.07.013
Jing‐Hui Yang, Ying Shen, Wei‐Di He, Nan Zhang, Ting Huang, Ji‐Hong Zhang, Yong Wang, None, Synergistic effect of poly(ethylene glycol) and graphene oxides on the crystallization behavior of poly(l‐lactide) Journal of Applied Polymer Science. ,vol. 130, pp. 3498- 3508 ,(2013) , 10.1002/APP.39371
Atif Islam, Tariq Yasin, Ihtesham ur Rehman, None, Synthesis of hybrid polymer networks of irradiated chitosan/poly(vinyl alcohol) for biomedical applications Radiation Physics and Chemistry. ,vol. 96, pp. 115- 119 ,(2014) , 10.1016/J.RADPHYSCHEM.2013.09.009