Photoemission from small Pd clusters on Al2O3 and SiO2 substrates

作者: Shigemi Kohiki , None

DOI: 10.1016/0169-4332(86)90027-9

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摘要: Abstract Positive core-electron binding energy shifts in small palladium clusters supported on Al 2 O 3 and SiO substrates are shown to arise predominantly from an initial-state effect that is more sensitive cluster size than a final-state lower coverage regions (Pd ⪅ 1×10 15 atoms cm -2 for ⪅1×10 14 ). The change of the extra-atomic relaxation larger directly correlates polarizability substrates.

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