Vinylphosphonic acid/methacrylamide system as a durable intumescent flame retardant for cotton fabric
作者： Giuseppe Rosace , Claudio Colleoni , Valentina Trovato , Giuseppina Iacono , Giulio Malucelli
DOI: 10.1007/S10570-017-1294-X
关键词:
摘要: A novel intumescent flame retardant treatment, consisting of vinylphosphonic acid (VPA) as the source and methacrylamide (MAA) blowing agent, was designed applied onto cotton fabrics. The grafting reactive monomers cellulose chains carried out using potassium persulfate initiator a radical polymerization technique. thermal fire behaviour treated fabrics thoroughly investigated: in particular, VPA/MAA coating able to exert protective action, giving rise formation stable swollen char on surface textile fibers upon heating, hence improving retardancy cotton. In addition, fabric achieved self-extinction assessed by horizontal spread tests. Finally, remarkable weight loss observed only after first washing cycle, then samples did not show any significant loss, confirming durability self-extinguishing even five laundering cycles.
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Roza M. Aseeva, Gennadiy E. Zaikov, Flammability of polymeric materials Springer, Berlin, Heidelberg. pp. 171- 229 ,(1985) , 10.1007/3-540-15481-7_10
S. Bourbigot, Flame retardancy of textiles: new approaches Advances in Fire Retardant Materials. pp. 9- 40 ,(2008) , 10.1533/9781845694701.1.9
Ana Maria Grancaric, Lea Botteri, Jenny Alongi, Giulio Malucelli, Synergistic effects occurring between water glasses and urea/ammonium dihydrogen phosphate pair for enhancing the flame retardancy of cotton Cellulose. ,vol. 22, pp. 2825- 2835 ,(2015) , 10.1007/S10570-015-0671-6
Gülten Gürdağ, Shokat Sarmad, Cellulose Graft Copolymers: Synthesis, Properties, and Applications Polysaccharide Based Graft Copolymers. pp. 15- 57 ,(2013) , 10.1007/978-3-642-36566-9_2
Claudio Morterra, M.J.D. Low, IR studies of carbons—IV The vacuum pyrolysis of oxidized cellulose and the characterization of the chars† Carbon. ,vol. 23, pp. 301- 310 ,(1985) , 10.1016/0008-6223(85)90115-0
C. Morterra, M.J.D. Low, A.G. Severdia, IR studies of carbons—III Carbon. ,vol. 22, pp. 5- 12 ,(1984) , 10.1016/0008-6223(84)90127-1
Jenny Alongi, Giulio Malucelli, Thermal Degradation of Cellulose and Cellulosic Substrates Reactions and Mechanisms in Thermal Analysis of Advanced Materials. ,vol. 1, pp. 301- 332 ,(2015) , 10.1002/9781119117711.CH14
M. I. Khalil, Kh. M. Mostafa, A. Hebeish, Graft polymerization of acrylamide onto maize starch using potassium persulfate as initiator Angewandte Makromolekulare Chemie. ,vol. 213, pp. 43- 54 ,(1993) , 10.1002/APMC.1993.052130106
P. Anna, Gy. Marosi, Gy. Bertalan, A. Márton, A. Szép, Structure-property relationship in flame retardant polymers Journal of Macromolecular Science, Part B. ,vol. 41, pp. 1321- 1330 ,(2002) , 10.1081/MB-120013102
Mazeyar Parvinzadeh Gashti, Arash Almasian, UV radiation induced flame retardant cellulose fiber by using polyvinylphosphonic acid/carbon nanotube composite coating Composites Part B-engineering. ,vol. 45, pp. 282- 289 ,(2013) , 10.1016/J.COMPOSITESB.2012.07.052