Impact of size control of graphene oxide nanosheets for enhancing electrical and mechanical properties of carbon nanotube–polymer composites

作者: Jeonghwan Kim , Sang Woo Kim , Hongseok Yun , Bumjoon J. Kim

DOI: 10.1039/C7RA04015F

关键词:

摘要: Graphene oxide (GO) has been explored for improving the dispersion stability of carbon nanotubes (CNTs). In particular, size and shape GO sheets have a significant impact on determining their efficiency optimizing properties CNT-based composites, but, to date, such effects never systematically assessed. this study, we evaluated GOs behavior multi-walled CNTs (MWCNTs), exploited them develop conducting film polymer–CNT composites with excellent electrical mechanical properties. Synthesis series five different varied sizes ranging from 170 2060 nm, but nearly same surface properties, allowed systematical investigation sheets. The CNT-dispersing ability was improved significantly as decreased. For example, critical GO-to-MWCNT ratio (WGO/WMWCNT) required produce stable MWCNT in proportion GO. Furthermore, minimum value WGO/WMWCNT fabricate conductive GO–MWCNT underwent dramatic decrease 0.1 0.025 changed nm. Small-sized facilitated formation an interconnected network more effectively than large-sized GOs. Further polymer–MWCNT performed by measuring Young's modulus composites. A two-fold enhancement achieved controlling Our results provide important guidelines design carbonaceous-material-based

参考文章(72)
Lei Jiang, Xiao-Ping Shen, Ji-Li Wu, Ke-Cheng Shen, Preparation and characterization of graphene/poly(vinyl alcohol) nanocomposites Journal of Applied Polymer Science. ,vol. 118, pp. 275- 279 ,(2010) , 10.1002/APP.32278
S. Bal, S. S. Samal, Carbon nanotube reinforced polymer composites-A state of the art Bulletin of Materials Science. ,vol. 30, pp. 379- 386 ,(2007) , 10.1007/S12034-007-0061-2
Jaemyung Kim, Laura J. Cote, Franklin Kim, Wa Yuan, Kenneth R. Shull, Jiaxing Huang, Graphene Oxide Sheets at Interfaces Journal of the American Chemical Society. ,vol. 132, pp. 8180- 8186 ,(2010) , 10.1021/JA102777P
L. Hu, J. W. Choi, Y. Yang, S. Jeong, F. La Mantia, L.-F. Cui, Y. Cui, Highly conductive paper for energy-storage devices Proceedings of the National Academy of Sciences of the United States of America. ,vol. 106, pp. 21490- 21494 ,(2009) , 10.1073/PNAS.0908858106
T. Hayashi, M. Endo, Carbon nanotubes as structural material and their application in composites Composites Part B-engineering. ,vol. 42, pp. 2151- 2157 ,(2011) , 10.1016/J.COMPOSITESB.2011.05.011
Michael D. Clark, Sachin Subramanian, Ramanan Krishnamoorti, Understanding surfactant aided aqueous dispersion of multi-walled carbon nanotubes Journal of Colloid and Interface Science. ,vol. 354, pp. 144- 151 ,(2011) , 10.1016/J.JCIS.2010.10.027
Jonathan N Coleman, Martin Cadek, Rowan Blake, Valeria Nicolosi, Kevin P Ryan, Colin Belton, Antonio Fonseca, Janos B Nagy, Yurii K Gun'ko, Werner J Blau, High Performance Nanotube‐Reinforced Plastics: Understanding the Mechanism of Strength Increase Advanced Functional Materials. ,vol. 14, pp. 791- 798 ,(2004) , 10.1002/ADFM.200305200
M. Cadek, J. N. Coleman, K. P. Ryan, V. Nicolosi, G. Bister, A. Fonseca, J. B. Nagy, K. Szostak, F. Béguin, W. J. Blau, Reinforcement of polymers with carbon nanotubes: The role of nanotube surface area Nano Letters. ,vol. 4, pp. 353- 356 ,(2004) , 10.1021/NL035009O
Jaemyung Kim, Laura J. Cote, Jiaxing Huang, Two Dimensional Soft Material: New Faces of Graphene Oxide Accounts of Chemical Research. ,vol. 45, pp. 1356- 1364 ,(2012) , 10.1021/AR300047S
Sung Ho Kim, Wooseok Song, Min Wook Jung, Min-A Kang, Kiwoong Kim, Sung-Jin Chang, Sun Sook Lee, Jongsun Lim, Jinha Hwang, Sung Myung, Ki-Seok An, Carbon Nanotube and Graphene Hybrid Thin Film for Transparent Electrodes and Field Effect Transistors Advanced Materials. ,vol. 26, pp. 4247- 4252 ,(2014) , 10.1002/ADMA.201400463