A photoemission study of benzotriazole on clean copper and cuprous oxide

作者: Bo-Shung Fang , Clifford G. Olson , David W. Lynch

DOI: 10.1016/0039-6028(86)90050-6

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摘要: Abstract Photoemission spectra of benzotriazole (BTA) chemisorbed on clean Cu and cuprous oxide were compared with the condensed- gas-phase BTA. Chemisorbed BTA bonds to both 2 O via lone-pair orbitais nitrogen ring. The lack a chemical shift for π- indicates that does not lie flat surface. We propose model geometry bonding which accounts its corrosion inhibition Cu, inhibition, or by molecules similar

参考文章(44)
Arthur D. Baker, C. R. Brundle, Electron spectroscopy : theory, techniques, and applications Academic Press. ,(1977)
M.W. Roberts, Photoelectron Spectroscopy and Surface Chemistry Advances in Catalysis. ,vol. 29, pp. 55- 95 ,(1980) , 10.1016/S0360-0564(08)60120-0
D. Chadwick, T. Hashemi, Benzotriazole adsorption on copper studied by X-ray photoelectron spectroscopy Journal of Electron Spectroscopy and Related Phenomena. ,vol. 10, pp. 79- 83 ,(1977) , 10.1016/0368-2048(77)85005-6
Kosaku Kishi, Fumiaki Kikui, Shigero Ikeda, Chemisorption bonds on nickel and palladium surfaces studied by substitution reactions of various organic molecules Surface Science Letters. ,vol. 99, pp. 405- 418 ,(1980) , 10.1016/0039-6028(80)90402-1
K. Bange, D.E. Grider, T.E. Madey, J.K. Sass, The surface chemistry of H2O on clean and oxygen-covered Cu(110) Surface Science. ,vol. 137, pp. 38- 64 ,(1984) , 10.1016/0167-2584(84)90207-X
J. E. Demuth, D. E. Eastman, Photoemission Observations of π-d Bonding and Surface Reactions of Adsorbed Hydrocarbons on Ni(111) Physical Review Letters. ,vol. 32, pp. 1123- 1127 ,(1974) , 10.1103/PHYSREVLETT.32.1123
K.Y. Yu, W.E. Spicer, I. Lindau, P. Pianetta, S.F. Lin, UPS studies of the bonding of H2, O2, CO, C2H4 and C2H2 on Fe and Cu☆ Surface Science. ,vol. 57, pp. 157- 183 ,(1976) , 10.1016/0039-6028(76)90175-8
D.C. Frost, C.A. McDowell, R.L. Tapping, Charge transfer-transitions and X-ray photoelectron spectroscopy of copper(II) complexes Journal of Electron Spectroscopy and Related Phenomena. ,vol. 6, pp. 347- 355 ,(1975) , 10.1016/0368-2048(75)80022-3
Chak-tong Au, Juraj Breza, M.Wyn Roberts, Hydroxylation and dehydroxylation at Cu(III) surfaces Chemical Physics Letters. ,vol. 66, pp. 340- 343 ,(1979) , 10.1016/0009-2614(79)85030-7