Determination of thermodynamic properties of sodium alginate from bacteria and seaweeds in aqueous solutions

作者: A. Straatmann , W. Borchard

DOI: 10.1007/3-540-44672-9_10

关键词:

摘要: Alginates are biopolymers produced by seaweeds as well some bacteria like Pseudomonas aeruginosa or Azotobacter vinelandii. They consist of copolymers containing 1,4-β-d-mannuronate and its 5-epimer α-l-guluronate. Their composition physical properties depend on the source alginate. Different alginates from have been investigated using analytical ultracentrifugation. The samples were prepared in sodium chloride solution to suppress charge effects polymers. From concentration gradient equilibrium centrifugation molar masses second virial coefficient derived. results obtained this method good agreement with light scattering measurements. different compared discussed.

参考文章(21)
V Körstgens, H.-C Flemming, J Wingender, W Borchard, Uniaxial compression measurement device for investigation of the mechanical stability of biofilms. Journal of Microbiological Methods. ,vol. 46, pp. 9- 17 ,(2001) , 10.1016/S0167-7012(01)00248-2
Abigail Ball, Stephen E. Harding, John R. Mitchell, Combined low speed sedimentation equilibrium/gel permeation chromatography approach to molecular weight distribution analysis: application to a sodium alginate International Journal of Biological Macromolecules. ,vol. 10, pp. 259- 264 ,(1988) , 10.1016/0141-8130(88)90001-3
H. Cölfen, Stephen E. Harding, MSTARA and MSTARI: interactive PC algorithms for simple, model independent evaluation of sedimentation equilibrium data European Biophysics Journal. ,vol. 25, pp. 333- 346 ,(1997) , 10.1007/S002490050047
H. Hinsken, W. Borchard, Continuous swelling pressure equilibria of the system κ-carrageenan/water Colloid and Polymer Science. ,vol. 273, pp. 913- 925 ,(1995) , 10.1007/BF00660368
David J. Wedlock, Peter A. Williams, Glyn O. Phillips, Gums and stabilisers for the food industry IRL Press at Oxford University Press. ,(1996)
Howard K Schachman, Ultracentrifugation in biochemistry ,(1959)
J Lee, Role of acetylation on metal induced precipitation of alginates Carbohydrate Polymers. ,vol. 29, pp. 337- 345 ,(1996) , 10.1016/S0144-8617(96)00017-3
David J. Wedlock, Badruddin A. Fasihuddin, Glyn O. Phillips, Comparison of molecular weight determination of sodium alginate by sedimentation-diffusion and light scattering International Journal of Biological Macromolecules. ,vol. 8, pp. 57- 61 ,(1986) , 10.1016/0141-8130(86)90072-3
Gudmund Skjåk-Bræk, Flavio Zanetti, Sergio Paoletti, Effect of acetylation on some solution and gelling properties of alginates Carbohydrate Research. ,vol. 185, pp. 131- 138 ,(1989) , 10.1016/0008-6215(89)84028-5