ω-Alkenyl-α-Methoxy-Benzyllithiums : Original Synthesis and Reactivity

作者: Alain Krief , Jamal Bousbaa

DOI: 10.1016/S0040-4039(97)01411-1

关键词:

摘要: 1-Methoxy-benzyllithiums bearing suitably positioned C,C double bonds possess a high propensity to produce five or six membered cycle by carbocyclisation reaction. The reaction proceeds completely stereoselectively and produces possessing the cis-stereochemistry between methoxy adjacent methyl group. © 1997 Published Elsevier Science Ltd.

参考文章(6)
Alain Krief, Benoĭt Kenda, Phillippe Barbeaux, Original reactions of α,α-dithio aryl alkanes with butyllithiums Tetrahedron Letters. ,vol. 32, pp. 2509- 2512 ,(1991) , 10.1016/S0040-4039(00)74368-1
Alain Krief, Philippe Barbeaux, Original syntheses of arylcycloalkanes Journal of The Chemical Society, Chemical Communications. pp. 1214- 1216 ,(1987) , 10.1039/C39870001214
E. C. Ashby, J. T. Laemmle, Stereochemistry of organometallic compound addition to ketones Chemical Reviews. ,vol. 75, pp. 521- 546 ,(1975) , 10.1021/CR60296A005
Katsuhiko Tomooka, Takeshi Nakai, [1, 2] -Wittig Rearrangement Stereochemical Features and Synthetic Utilities Journal of Synthetic Organic Chemistry Japan. ,vol. 54, pp. 1000- 1008 ,(1996) , 10.5059/YUKIGOSEIKYOKAISHI.54.1000
A. Krief, P. Barbeaux, E. Guittet, Novel Stereoselective Synthesis of Arylcyclopropanes Synlett. ,vol. 1990, pp. 509- 510 ,(1990) , 10.1055/S-1990-21145