Oxygen Vacancies Dominated NiS2/CoS2 Interface Porous Nanowires for Portable Zn–Air Batteries Driven Water Splitting Devices
作者： Jie Yin , Yuxuan Li , Fan Lv , Min Lu , Ke Sun
关键词:
摘要: The development of highly active and stable oxygen evolution reaction (OER) electrocatalysts is crucial for improving the efficiency water splitting metal-air battery devices. Herein, an efficient strategy demonstrated making vacancies dominated cobalt-nickel sulfide interface porous nanowires (NiS2 /CoS2 -O NWs) boosting OER catalysis through in situ electrochemical NiS2 NWs. Because abundant structure, they can catalyze efficiently with a low overpotential 235 mV at j = 10 mA cm-2 remarkable long-term stability 1.0 m KOH. home-made rechargeable portable Zn-air batteries by using NWs as air-cathode display very high open-circuit voltage 1.49 V, which maintain more than 30 h. Most importantly, self-driven device designed both anode cathode, powered two-series-connected NWs-based batteries. present work opens new way designing multifunctional reactions renewable energy
sci-hub.se 参考文章(54)
Sheng-Cai Zhu, Shu-Hui Guan, Wei-Na Zhao, Zhi-Pan Liu, Atomic Structure of Heterophase Junction from Theoretical Prediction Topics in Catalysis. ,vol. 58, pp. 644- 654 ,(2015) , 10.1007/S11244-015-0410-0
Pengzuo Chen, Kun Xu, Zhiwei Fang, Yun Tong, Junchi Wu, Xiuli Lu, Xu Peng, Hui Ding, Changzheng Wu, Yi Xie, Metallic Co4N Porous Nanowire Arrays Activated by Surface Oxidation as Electrocatalysts for the Oxygen Evolution Reaction Angewandte Chemie. ,vol. 54, pp. 14710- 14714 ,(2015) , 10.1002/ANIE.201506480
Sheng Chen, Jingjing Duan, Mietek Jaroniec, Shi-Zhang Qiao, Nitrogen and Oxygen Dual-Doped Carbon Hydrogel Film as a Substrate-Free Electrode for Highly Efficient Oxygen Evolution Reaction Advanced Materials. ,vol. 26, pp. 2925- 2930 ,(2014) , 10.1002/ADMA.201305608
Fengcai Lei, Yongfu Sun, Katong Liu, Shan Gao, Liang Liang, Bicai Pan, Yi Xie, Oxygen vacancies confined in ultrathin indium oxide porous sheets for promoted visible-light water splitting. Journal of the American Chemical Society. ,vol. 136, pp. 6826- 6829 ,(2014) , 10.1021/JA501866R
J. A. Turner, Sustainable Hydrogen Production Science. ,vol. 305, pp. 972- 974 ,(2004) , 10.1126/SCIENCE.1103197
Xihong Lu, Gongming Wang, Teng Zhai, Minghao Yu, Jiayong Gan, Yexiang Tong, Yat Li, Hydrogenated TiO2 Nanotube Arrays for Supercapacitors Nano Letters. ,vol. 12, pp. 1690- 1696 ,(2012) , 10.1021/NL300173J
Yan Jiao, Yao Zheng, Mietek Jaroniec, Shi Zhang Qiao, Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions Chemical Society Reviews. ,vol. 44, pp. 2060- 2086 ,(2015) , 10.1039/C4CS00470A
Yanguang Li, Ming Gong, Yongye Liang, Ju Feng, Ji-Eun Kim, Hailiang Wang, Guosong Hong, Bo Zhang, Hongjie Dai, Advanced zinc-air batteries based on high-performance hybrid electrocatalysts Nature Communications. ,vol. 4, pp. 1805- 1805 ,(2013) , 10.1038/NCOMMS2812
Matthea A. Peck, Marjorie A. Langell, Comparison of Nanoscaled and Bulk NiO Structural and Environmental Characteristics by XRD, XAFS, and XPS Chemistry of Materials. ,vol. 24, pp. 4483- 4490 ,(2012) , 10.1021/CM300739Y
Mark K. Debe, Electrocatalyst approaches and challenges for automotive fuel cells Nature. ,vol. 486, pp. 43- 51 ,(2012) , 10.1038/NATURE11115