Growth of molybdenum carbide micro-islands on carbon cloth toward binder-free cathodes for efficient hydrogen evolution reaction
作者： Meihong Fan , Hui Chen , Yuanyuan Wu , Liang-Liang Feng , Yipu Liu
DOI: 10.1039/C5TA03500G
关键词:
摘要: Design and synthesis of efficient noble metal-free hydrogen evolution catalysts is of paramount importance for the practical application of water-splitting devices. Herein, we report a novel synthetic method to grow dispersed molybdenum carbide (Mo2C) micro-islands on flexible carbon cloth (CC). This method involves the controlled synthesis of a supramolecular hybrid between cetyltrimethyl ammonium cations and molybdate anions on CC, followed by simple thermal treatment of this supramolecular hybrid in Ar to form Mo2C …
rsc.org
sci-hub.se 
researchgate.net 参考文章(56)
Peng Xiao, Mahasin Alam Sk, Larissa Thia, Xiaoming Ge, Rern Jern Lim, Jing-Yuan Wang, Kok Hwa Lim, Xin Wang, Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction Energy and Environmental Science. ,vol. 7, pp. 2624- 2629 ,(2014) , 10.1039/C4EE00957F
Jiao Deng, Pengju Ren, Dehui Deng, Liang Yu, Fan Yang, Xinhe Bao, Highly active and durable non-precious-metal catalysts encapsulated in carbon nanotubes for hydrogen evolution reaction Energy and Environmental Science. ,vol. 7, pp. 1919- 1923 ,(2014) , 10.1039/C4EE00370E
Michael G. Walter, Emily L. Warren, James R. McKone, Shannon W. Boettcher, Qixi Mi, Elizabeth A. Santori, Nathan S. Lewis, Solar Water Splitting Cells Chemical Reviews. ,vol. 110, pp. 6446- 6473 ,(2010) , 10.1021/CR1002326
Zhenglong Li, Shantanu Kelkar, Lauren Raycraft, Mahlet Garedew, James E. Jackson, Dennis J. Miller, Christopher M. Saffron, A mild approach for bio-oil stabilization and upgrading: electrocatalytic hydrogenation using ruthenium supported on activated carbon cloth Green Chemistry. ,vol. 16, pp. 844- 852 ,(2014) , 10.1039/C3GC42303D
Yao Zheng, Yan Jiao, Yihan Zhu, Lu Hua Li, Yu Han, Ying Chen, Aijun Du, Mietek Jaroniec, Shi Zhang Qiao, Hydrogen evolution by a metal-free electrocatalyst Nature Communications. ,vol. 5, pp. 3783- ,(2014) , 10.1038/NCOMMS4783
O. Einsle, Nitrogenase MoFe-Protein at 1.16 A Resolution: A Central Ligand in the FeMo-Cofactor Science. ,vol. 297, pp. 1696- 1700 ,(2002) , 10.1126/SCIENCE.1073877
Chun Tang, Zonghua Pu, Qian Liu, Abdullah M Asiri, Xuping Sun, None, NiS2 nanosheets array grown on carbon cloth as an efficient 3D hydrogen evolution cathode Electrochimica Acta. ,vol. 153, pp. 508- 514 ,(2015) , 10.1016/J.ELECTACTA.2014.12.043
Ping Liu, José A. Rodriguez, Catalysts for hydrogen evolution from the [NiFe] hydrogenase to the Ni2P(001) surface: the importance of ensemble effect. Journal of the American Chemical Society. ,vol. 127, pp. 14871- 14878 ,(2005) , 10.1021/JA0540019
Hong-Bin Yao, Xiao-Bo Li, Shu-Juan Liu, Shu-Hong Yu, Lamellar transition-metal molybdate–CTA mesostructured composites (metal = Ni, Co): one-pot synthesis and application in treatment of acid fuchsine Chemical Communications. pp. 6732- 6734 ,(2009) , 10.1039/B914329G
Douglas C Rees, James B Howard, The interface between the biological and inorganic worlds: iron-sulfur metalloclusters. Science. ,vol. 300, pp. 929- 931 ,(2003) , 10.1126/SCIENCE.1083075